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  1. Russian Journal of Physical Chemistry B
  2. Russian Journal of Physical Chemistry B : Volume 10
  3. Russian Journal of Physical Chemistry B : Volume 10, Issue 5, September 2016
  4. Ignition and combustion of isopropyl nitrate
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Russian Journal of Physical Chemistry B : Volume 11
Russian Journal of Physical Chemistry B : Volume 10
Russian Journal of Physical Chemistry B : Volume 10, Issue 8, December 2016
Russian Journal of Physical Chemistry B : Volume 10, Issue 7, December 2016
Russian Journal of Physical Chemistry B : Volume 10, Issue 6, November 2016
Russian Journal of Physical Chemistry B : Volume 10, Issue 5, September 2016
Elementary supramolecular strings in solutions of chiral trifluoroacetylated amino alcohols
IR photoluminescence of Bi$^{+}$ impurity centers in the RbY$_{2}$Cl$_{7}$ ternary chloride
An improved method for selective catalytic reduction of nitrogen oxides in exhaust gases
Chemical kinetic model of the chain reaction of atmospheric nitrogen oxidation initiated by electric discharge
Method of solving the inverse problem of chemical kinetics for catalytic reactions in which each step involves main reactants
Ammonia decomposition on a platinum nanocoating at various electric potentials
Oxidation of the aniline–styrene epoxide-p-toluenesulfonic acid ternary system in polar solvents: Trends and mechanism
Initiation of combustion in multilayer energetic compositions with a high-current electron beam
Effect of a ceramic coating on the characteristic of surface combustion
Ignition and combustion of isopropyl nitrate
On a nonstationary theory of thermal explosion in a semi-batch reactor. Homogeneous systems
Influence of the heat loss intensity on the characteristics of the filtration combustion of solid organic fuels
Spectrokinetic characteristics of light emission from pentaerythritol tetranitrate single crystals detonating under the action of a high-current electron beam
A detailed kinetic mechanism of multistage oxidation and combustion of isooctane
Features of the electrical and photoelectrical properties of nanocrystalline indium and zinc oxide films
Effect of femtosecond laser radiation on mammalian oocytes
Restructuring of polytetrafluoroethylene films during crazing in liquid media as an effective sorption method
Thermal oxidation and structure of polylactide–polyethylene blends
Electrospinning of biodegradable poly-3-hydroxybutyrate. Effect of the characteristics of the polymer solution
Molecular mobility of nanocellulose hydrogels
Transport properties of bilayer graphene nanoribbons with hydrogen adatoms
Gas–surface reactions in the growth of dielectric films by chemical vapor deposition: The role of nonequilibrium surface diffusion of adsorbed precursors
Chlorine activation of the lower stratosphere at mid-latitudes: Impact on the ozone layer
Russian Journal of Physical Chemistry B : Volume 10, Issue 4, July 2016
Russian Journal of Physical Chemistry B : Volume 10, Issue 2, March 2016
Russian Journal of Physical Chemistry B : Volume 10, Issue 1, January 2016
Russian Journal of Physical Chemistry B : Volume 9
Russian Journal of Physical Chemistry B : Volume 8
Russian Journal of Physical Chemistry B : Volume 7
Russian Journal of Physical Chemistry B : Volume 6
Russian Journal of Physical Chemistry B : Volume 5
Russian Journal of Physical Chemistry B : Volume 4
Russian Journal of Physical Chemistry B : Volume 3
Russian Journal of Physical Chemistry B : Volume 2
Russian Journal of Physical Chemistry B : Volume 1

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Ignition and combustion of isopropyl nitrate

Content Provider Springer Nature Link
Author Borisov, A. A. Troshin, K. Ya. Mikhalkin, V. N.
Copyright Year 2016
Abstract The ignition delay times for mixtures of isopropyl nitrate (IPN) with air and argon are measured in a rapid-injection reactor at a pressure of 1 atm and in a shock tube at 2–3 atm. It is shown that the ignition delay time τ of mixtures in which heat is largely released due to oxidation by the oxygen contained in the IPN molecule is determined by the unimolecular decomposition of IPN over the entire temperature range covered (500–730 K). For mixtures in which heat is mainly produced by oxidation reactions involving air oxygen, the ignition delay time at high temperatures is controlled by secondary reactions of oxidation of the hydrocarbon moiety of the IPN molecule, leading to an increase in τ by more than an order of magnitude. Liquid IPN burns in a nitrogen atmosphere only at pressures above 40 atm, at a linear rate of ~4 mm/s. The measured flame temperatures are in close agreement with the respective values calculated using a thermodynamic code.
Starting Page 780
Ending Page 784
Page Count 5
File Format PDF
ISSN 19907931
Journal Russian Journal of Physical Chemistry B
Volume Number 10
Issue Number 5
e-ISSN 19907923
Language English
Publisher Pleiades Publishing
Publisher Date 2016-11-12
Publisher Place Moscow
Access Restriction One Nation One Subscription (ONOS)
Subject Keyword isopropyl nitrate ignition delay combustion Physical Chemistry
Content Type Text
Resource Type Article
Subject Physical and Theoretical Chemistry
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