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| Content Provider | Springer Nature Link |
|---|---|
| Author | Gao, Jihui Chen, Guoqing Fu, Xiaolin Yin, Yijun Wu, Shaohua Qin, Yukun |
| Copyright Year | 2011 |
| Abstract | The enhancement mechanism of SO$_{2}$ removal by the presence of NO$_{2}$ under low temperature and humid conditions was studied in a fixed bed reactor system. The presence of NO$_{2}$ in the flue gas can enhance SO$_{2}$ removal. The interaction between SO$_{2}$ and NO$_{2}$ in gas phase could not explain the effect of NO$_{2}$ on SO$_{2}$ removal under low-temperature and humid conditions. When Ca(NO$_{3}$)$_{2}$ and Ca(NO$_{2}$)2 as additive were added on the surface of sorbent, the desulfurization activity of sorbent decreased. However, the sorbent pretreated by NO$_{2}$ for a moment has higher SO$_{2}$ removal. The oxidization of SO 3 2− to SO 4 2− and the evolution of sorbent surface structure in the presence of NO$_{2}$ can explain the enhancement of SO$_{2}$ removal by the presence of NO$_{2}$. HSO 3 − and SO 3 − reacted with NO$_{2}$ to form sulfate, which can accelerate the hydrolysis of SO$_{2}$. The reaction between NO$_{2}$ and Ca(OH)$_{2}$ can make the unreacted sorbet under the SO$_{2}$ removal product exposed to the reactant gas. |
| Starting Page | 263 |
| Ending Page | 269 |
| Page Count | 7 |
| File Format | |
| ISSN | 02561115 |
| Journal | Korean Journal of Chemical Engineering |
| Volume Number | 29 |
| Issue Number | 2 |
| e-ISSN | 19757220 |
| Language | English |
| Publisher | Springer US |
| Publisher Date | 2011-12-24 |
| Publisher Place | Boston |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | SO$_{2}$ and NO$_{2}$ Desulfurization Denitrification Flue Gas Calcium Hydroxide Biotechnology Industrial Chemistry/Chemical Engineering Materials Science Catalysis |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Chemical Engineering |
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