NDLI: Photocatalytic degradation of benzene, toluene, ethylbenzene, and xylene (BTEX) using transition metal-doped titanium dioxide immobilized on fiberglass cloth

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Photocatalytic degradation of benzene, toluene, ethylbenzene, and xylene (BTEX) using transition metal-doped titanium dioxide immobilized on fiberglass cloth

Content Provider	Springer Nature Link
Author	Laokiat, Laksana Khemthong, Pongtanawat Grisdanurak, Nurak Sreearuthai, Paiboon Pattanasiriwisawa, Wanwisa Klysubun, Wantana
Copyright Year	2011
Abstract	Transition metal (Fe, V and W)-doped TiO$_{2}$ was synthesized via the solvothermal technique and immobilized onto fiberglass cloth (FGC) for uses in photocatalytic decomposition of gaseous volatile organic compounds—benzene, toluene, ethylbenzene and xylene (BTEX)—under visible light. Results were compared to that of the standard commercial pure TiO$_{2}$ (P25) coated FGC. All doped samples exhibit higher visible light catalytic activity than the pure TiO$_{2}$. The V-doped sample shows the highest photocatalytic activity followed by the W- and Fe-doped samples. The UV-Vis diffuse reflectance spectra reveal that the V-doped sample has the highest visible light absorption followed by the W- and Fe-doped samples. The X-ray diffraction (XRD) patterns indicate that all doped samples contain both anatase and rutile phases with the majority (>80%) being anatase. No new peaks associated with dopant oxides can be observed, suggesting that the transition metal (TM) dopants are well mixed into the TiO$_{2}$ lattice, or are below the detection limit of the XRD. The X-ray absorption near-edge structure spectra of the Ti K-edge transition indicate that most Ti ions are in a tetravalent state with octahedral coordination, but with increased lattice distortion from Fe- to V- and W-doped samples. Our results show that the TM-doped TiO$_{2}$ were successfully synthesized and immobilized onto flexible fiberglass cloth suitable for treatment of gaseous organic pollutants under visible light.
Starting Page	377
Ending Page	383
Page Count	7
File Format	PDF
ISSN	02561115
Journal	Korean Journal of Chemical Engineering
Volume Number	29
Issue Number	3
e-ISSN	19757220
Language	English
Publisher	Springer US
Publisher Date	2011-12-05
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Photocatalytic Degradation BTEX Transition Metal-doped TiO$_{2}$ Materials Science Biotechnology Industrial Chemistry/Chemical Engineering Catalysis
Content Type	Text
Resource Type	Article
Subject	Chemistry Chemical Engineering

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