NDLI: Density, ultrasonic velocity, viscosity and their excess parameters of the binary mixtures of N,N-dimethylaniline+1-alkanols (C$_{3}$-C$_{5}$), +2-alkanols (C$_{3}$-C$_{4}$), +2-methyl-1-propanol, +2-methyl-2-propanol at 303.15K

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Density, ultrasonic velocity, viscosity and their excess parameters of the binary mixtures of N,N-dimethylaniline+1-alkanols (C$_{3}$-C$_{5}$), +2-alkanols (C$_{3}$-C$_{4}$), +2-methyl-1-propanol, +2-methyl-2-propanol at 303.15K

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Density, ultrasonic velocity, viscosity and their excess parameters of the binary mixtures of N,N-dimethylaniline+1-alkanols (C$_{3}$-C$_{5}$), +2-alkanols (C$_{3}$-C$_{4}$), +2-methyl-1-propanol, +2-methyl-2-propanol at 303.15K

Content Provider	Springer Nature Link
Author	Manukonda, Gowrisankar Ponneri, Venkateswarlu Kasibhatta, Sivakumar Sakamuri, Sivarambabu
Copyright Year	2013
Abstract	The density, ultrasonic velocity of sound and viscosity of binary mixtures of N,N-dimethyl aniline (N,NDMA) with 1-propanol, +2-propanol, +1-butanol, +2-butanol, +1-pentanol, +2-methyl-1-propanol, +2-methyl-2-propanol were measured at 303.15 K. These experimental data have been used to calculate excess volume V$^{ E }$, excess ultrasonic speeds u$^{ E }$, excess intermolecular free length L f E , excess acoustic impedance Z$^{ E }$, excess isentropic compressibility κ s E , deviation in viscosity Δη and excess Gibbs free energy of activation of viscous flow (G*$^{ E }$). The values of L f E and κ s E are negative over the wide range of composition for all the binary mixtures, while the values of Z$^{ E }$ are positive. These results have been used to discuss the nature of interaction between unlike molecules in terms of hydrogen bonding, dipole-dipole interaction, proton-acceptor interaction and dispersive forces. The viscosity data have been correlated using three equations: Grunberg and Nissan, Katti & Chaudhri and Hind et al. The excess/deviations were fitted by a Redlich-Kister equation and the results were analyzed in terms of specific interactions present in these mixtures.
Starting Page	1131
Ending Page	1141
Page Count	11
File Format	PDF
ISSN	02561115
Journal	Korean Journal of Chemical Engineering
Volume Number	30
Issue Number	5
e-ISSN	19757220
Language	English
Publisher	Springer US
Publisher Date	2013-04-20
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Ultrasonic Velocity Viscosity Density Excess Thermodynamic Parameters Industrial Chemistry/Chemical Engineering Catalysis Materials Science Biotechnology
Content Type	Text
Resource Type	Article
Subject	Chemistry Chemical Engineering

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