NDLI: Adsorption behavior of aqueous europium on kaolinite under various disposal conditions

Content Provider	Springer Nature Link
Author	Kang, Mun Ja Hahn, Pil Soo
Copyright Year	2004
Abstract	This work investigated the adsorption behavior of europium on kaolinite under various disposal conditions. Batch-wise adsorption and precipitation experiments and equilibrium model calculations were performed over a pH range of 4–10 and CO$_{2}$ concentration range of 0%, 0.03%, and 10%. Experimental precipitation behaviors are in agreement with the results of equilibrium model calculations using the geochemical code MINTEQA2. Aqueous species of Eu$^{3+}$ exists mainly at pH 5 or below and solid phases of Eu(OH)$_{3}$(s), Eu(OH)CO$_{3}$(s), and Eu$_{2}$(CO$_{3}$)$_{3}$·3H$_{2}$O(s) are formed at higher pH ranges. Adsorption behavior of Eu on kaolinite in the low pH range can be explained by interlayer ion-exchange reaction. The significant increase in adsorbed amount at pH 5–6 is due to the surface complexation at the edge site of kaolinite. In the high pH range, precipitation of Eu contributes mainly to the adsorption quantity. The rapid decrease in adsorbed amount above pH 7 under 10% CO$_{2}$ condition occurs by the formation of anionic europium species of Eu(CO$_{3}$) 2 - .The adsorption of Eu on kaolinite could be well interpreted by the Freundlich adsorption isotherm. The data except for the highest equilibrium concentration ranges were also explained by Langmuir isotherm and the maximum adsorbed quantity of Eu on kaolinite,b, is 1.2 mg/g.
Starting Page	419
Ending Page	424
Page Count	6
File Format	PDF
ISSN	02561115
Journal	Korean Journal of Chemical Engineering
Volume Number	21
Issue Number	2
e-ISSN	19757220
Language	English
Publisher	Springer-Verlag
Publisher Date	2004-01-01
Publisher Place	Berlin, Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Europium Species Adsorption Kaolinite Industrial Chemistry/Chemical Engineering Catalysis Materials Science Biotechnology
Content Type	Text
Resource Type	Article
Subject	Chemistry Chemical Engineering

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