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Corrosion behavior of anodic oxidized TiO$_{2}$ film in seawater

Content Provider	Springer Nature Link
Author	Wang, Min Wang, Wei He, Benlin Sun, Mingliang Yin, Yansheng Liu, Lan Zou, Wuyuan Xu, Xuefei
Copyright Year	2010
Abstract	TiO$_{2}$ films were formed on metallic titanium substrates by the anodic oxidation method in H$_{2}$SO$_{4}$ solution under the 80V D.C.. Phase component and microstructure were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Water contact angles on titanium oxide film surface were measured under both dark and sunlight illumination conditions. Corrosion tests were carried out in seawater under different illumination conditions by electrochemistry impedance spectrum (EIS) and polarization curves. The result showed that the TiO$_{2}$ film prepared by the anodic oxidation method was anatase with a uniform structure and without obvious pores or cracks on its surface. The average water contact angle of the film was 116.4° in dark, in contrast to an angle of 42.7° under the UV illumination for 2 hours, which demonstrates good hydrophobic property. The anti-corrosion behavior of the TiO$_{2}$ film was declining with the extended immersion time. Under dark conditions, however, the hydrophobic TiO$_{2}$ film retarded the water infiltrating into the substrate. The impedance changed slowly and the corrosion current density was 2 orders of magnitude lower than that with the film illuminated by sunlight. All of those mentioned above indicate that the TiO$_{2}$ film possesses much better performance under dark condition, and it can be applied as an engineering material under dark seawater environment.
Starting Page	376
Ending Page	380
Page Count	5
File Format	PDF
ISSN	16725182
Journal	Journal of Ocean University of China
Volume Number	9
Issue Number	4
e-ISSN	19935021
Language	English
Publisher	SP Science Press
Publisher Date	2010-10-30
Publisher Place	Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	TiO$_{2}$ film anodic oxidation method hydrophobic corrosion resistance electrochemistry impedance spectrum (EIS) Oceanography
Content Type	Text
Resource Type	Article
Subject	Oceanography Ocean Engineering

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