NDLI: Applications of protecting groups in the synthesis of surfactants, lipids, and related compounds

Content Provider	Springer Nature Link
Author	Urata, Kouichi Takaishi, Naotake
Copyright Year	1998
Abstract	Several types of alkyl ether lipids were prepared in high yield and high purity using protecting groups such as 1,3-dioxolane compounds or allyl ethers. We also succeeded in the industrial production of alkyl glyceryl ethers using the reaction of alkyl glycidyl ethers with acetone to give 1,3-dioxolane compounds, from which the desired alkyl glyceryl ethers were obtained in high quantities. 1,3-Dioxolane (ketal) compounds based on acetone were used in the enzymatic preparation of monoglyceride on an industrial scale. On the basis of these protecting groups, we extended our studies concerning both the preparations and properties of novel polyol ether compounds, beginning with alkyl glycidyl ethers. Another typical property of surfactants containing 1,3-dioxolane units and acetal is degradability under acidic conditions. Several types of destructible/cleavable surfactants based on polyols, such as carbohydrates and polyethyleneglycol, were prepared. As for natural products containing polyol skeletons, much attention has been paid to their molecular design, in which protecting groups such as 1,3-dioxolane compounds or allyl ether have contributed to synthetic strategies.
Starting Page	73
Ending Page	82
Page Count	10
File Format	PDF
ISSN	10973958
Journal	Journal of Surfactants and Detergents
Volume Number	1
Issue Number	1
e-ISSN	15589293
Language	English
Publisher	Springer-Verlag
Publisher Date	1998-01-01
Publisher Place	Berlin, Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Acetal allyl ether dioxolane compound glyceryl ether ketal lipid protecting group surfactant Analytical Chemistry Physical Chemistry Polymer Sciences Industrial Chemistry/Chemical Engineering Surfaces and Interfaces, Thin Films Waste Water Technology Water Pollution Control Water Management Aquatic Pollution
Content Type	Text
Resource Type	Article
Subject	Surfaces, Coatings and Films Physical and Theoretical Chemistry Chemical Engineering

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