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| Content Provider | Springer Nature Link |
|---|---|
| Author | Li, Hai bin Tian, Zhen Wang, Meng Zhang, Ai ying Feng, Zeng guo |
| Copyright Year | 2008 |
| Abstract | Bioactive and biodegradable polyurethanes (BDPUs) have drawn much attention in recent years. As part of the research program to search for novel prepolymers for BDPUs, a study was carried out on the synthesis and characterization of triblock copolymers comprising poly(tetrahydrofuran) as a central block and poly(γ-benzyl L-glutamate)s as outer blocks.A new macroinitiator terminated with phenylalanine was first prepared from the condensation of a distal hydroxy poly(tetrahydrofuran) with N-tert-butoxycarbonyl L-phenylalanine in the presence of dicyclohexylcarbodiimide, followed by removing the protecting group. Then, it was employed to initiate the ring-opening polymerization of γ-benzyl L-glutamate N-carboxyanhydride in varying feeding ratios to give rise to the targeted triblock copolymers.The length of the outer poly(γ-benzyl L-glutamate) blocks was well tailored by varying the monomers to macroinitiator feeding ratio. All the triblock copolymers exhibited a nearly symmetrical and unimodal molecular weight distribution while only one distinct glass transition temperature was evidenced from −10°C to 25°C. |
| Starting Page | 84 |
| Ending Page | 90 |
| Page Count | 7 |
| File Format | |
| ISSN | 16737377 |
| Journal | Frontiers of Materials Science in China |
| Volume Number | 2 |
| Issue Number | 1 |
| e-ISSN | 16737482 |
| Language | English |
| Publisher | SP Higher Education Press |
| Publisher Date | 2008-03-20 |
| Publisher Institution | Chinese Universities |
| Publisher Place | Heidelberg |
| Access Restriction | Subscribed |
| Subject Keyword | γ-benzyl L-glutamate N-carboxyanhydride (BLG-NCA) phenylalanine end-capped macroinitiator poly(tetrahydrofuran) (PTHF) ring-opening polymerization (ROP) triblock polypeptide copolymer Materials Science |
| Content Type | Text |
| Resource Type | Article |
| Subject | Materials Science |
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