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| Content Provider | Springer Nature Link |
|---|---|
| Author | Vuong, Son Nguyen Dang, Ha My Tran, Quang Thinh Luong, Thi Thu Thuy Pham, Trang T. T. Nguyen Tran, Thuat Mai, Anh Tuan |
| Copyright Year | 2017 |
| Abstract | This study investigates the performance of dye-sensitized solar cells (DSSC) based on a copper(I) complex. A simple form of copper(I) complex dye was synthesized with a structure of [Cu(L)(CH$_{3}$CN)], where L is the 6,6′-dimethyl-4,4′-bis(phenylethynyl)-2,2′-bipyridine ligand. The full structure of DSSC investigated in this study is as follows: FTO/TiO$_{2}$/dye Cu(I) bipyridyl/3I$^{−}$/I$_{3}$ $^{−}$ electrolyte/graphite/FTO. The TiO$_{2}$ photoanodes were deposited from apoly(vinylpyrrolidone)-based paste using a spin coating technique. Different conditions of fabrication, such as paste dispersion time and total TiO$_{2}$ thickness, were systematically studied in order to optimize the performance of the DSSC. The trigonal planar complex [Cu(L)CH$_{3}$CN] was revealed to be suitable for applications in DSSC. The highest exhibited short circuit current density was found to be 0.48 mA/cm$^{2}$, with an open voltage of 477 mV, a form factor of 34% and a power conversion efficiency of 0.08% for the cell with photoanodes thickness of about 2.2 μm. It was shown that the dye and the paste formulation had great potential for applications in DSSC. |
| Starting Page | 3639 |
| Ending Page | 3645 |
| Page Count | 7 |
| File Format | |
| ISSN | 03615235 |
| Journal | Journal of Electronic Materials |
| Volume Number | 46 |
| Issue Number | 6 |
| e-ISSN | 1543186X |
| Language | English |
| Publisher | Springer US |
| Publisher Date | 2017-01-05 |
| Publisher Place | New York |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Copper(I) bipyridyl dye sensitized solar cells poly(vinylpyrrolidone) TiO$_{2}$ paste Optical and Electronic Materials Characterization and Evaluation of Materials Electronics and Microelectronics, Instrumentation Solid State Physics |
| Content Type | Text |
| Resource Type | Article |
| Subject | Materials Chemistry Electronic, Optical and Magnetic Materials Condensed Matter Physics Electrical and Electronic Engineering |
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