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| Content Provider | Springer Nature Link |
|---|---|
| Author | Shi, Cheng Bin Yu, Wen Tao Wang, Hao Li, Jing Jiang, Min |
| Copyright Year | 2016 |
| Abstract | Calcium modification of both alumina and MgO·Al$_{2}$O$_{3}$ inclusions during protective gas electroslag remelting (P-ESR) of 8Cr17MoV stainless steel and its effect on nitrides and primary carbides were studied by analyzing the transient evolution of oxide and sulfide inclusions in the P-ESR process. The oxide inclusions that were not removed during P-ESR without calcium treatment were found to retain their original state until in as-cast ingot. Calcium treatment modified all MgO·Al$_{2}$O$_{3}$ and alumina inclusions that had not been removed in the P-ESR process to liquid/partially liquid CaO-Al$_{2}$O$_{3}$-(MgO) with uniformly distributed elements, in addition to a small proportion of partially modified inclusions of a CaO-MgO-Al$_{2}$O$_{3}$ core surrounded by a liquid CaO-Al$_{2}$O$_{3}$. The modification of low-MgO-containing MgO·Al$_{2}$O$_{3}$ inclusions involves the preferential reduction of MgO from the MgO·Al$_{2}$O$_{3}$ inclusion by calcium and the reaction of calcium with Al$_{2}$O$_{3}$ in the inclusion. It is the incomplete/complete reduction of MgO from the spinel by calcium that contributes to the modification of spinels. Alumina inclusions were liquefied by direct reaction with calcium. Calcium treatment during P-ESR refining also provided an effective approach to prevent the formation of nitrides and primary carbides in stainless steel through modifying their preferred nucleation sites (alumina and MgO·Al$_{2}$O$_{3}$ inclusions) to calcium aluminates, which made no contribution to improving the steel cleanliness. |
| Starting Page | 146 |
| Ending Page | 161 |
| Page Count | 16 |
| File Format | |
| ISSN | 10735615 |
| Journal | Metallurgical and Materials Transactions B |
| Volume Number | 48 |
| Issue Number | 1 |
| e-ISSN | 15431916 |
| Language | English |
| Publisher | Springer US |
| Publisher Date | 2016-08-29 |
| Publisher Place | New York |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Metallic Materials Characterization and Evaluation of Materials Structural Materials Surfaces and Interfaces, Thin Films Nanotechnology |
| Content Type | Text |
| Resource Type | Article |
| Subject | Materials Chemistry Metals and Alloys Mechanics of Materials Condensed Matter Physics |
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