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A novel modification approach for natural graphite anode of Li-ion batteries

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A novel modification approach for natural graphite anode of Li-ion batteries

Content Provider	Springer Nature Link
Author	Zhou, Xiang yang Li, Jie Liu, Hong zhuan Liu, Ye xiang
Copyright Year	2004
Abstract	To improve the rate capability and cyclability of natural graphite anode for Li-ion batteries, a novel modification approach was developed. The modification approach included two steps: (a) high-energy ball milling in a rotary autoclave containing alumina balls, H$_{3}$ PO$_{4}$ and ethanol; (b) coating with pyrolytic carbon from phenlic resin. The treated graphite shows obvious improvement compared with the original natural graphite in electrochemical properties such as cyclability and rate capability, especially at high current density. The primary reasons leading to the improvement in rate capability and cyclability are that the diffusion impedance of Li$^{+}$ in graphite is reduced due to the fact that P filtered into graphite layers can mildly increase interlayer distances, and the fact that the structural stability of graphite surface is enhanced since the coated pyrolytic carbon can depress the co-intercalation of solvated lithium ion.
Starting Page	85
Ending Page	89
Page Count	5
File Format	PDF
ISSN	10002413
Journal	Journal of Wuhan University of Technology-Mater. Sci. Ed.
Volume Number	19
Issue Number	2
Language	English
Publisher	Wuhan University of Technology
Publisher Date	2004-01-01
Publisher Place	Wuhan
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Li-ion batteries natural graphite anode high-energy ball milling coating pyrolytic carbon Materials Science
Content Type	Text
Resource Type	Article
Subject	Materials Science

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A novel modification approach for natural graphite anode of Li-ion batteries

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