NDLI: The optimization of synthesizing graft copolymer of starch with vinyl monomers

Content Provider	Springer Nature Link
Author	Zhiyu, Wang Zuoxin, Liu
Copyright Year	2005
Abstract	The graft copolymerization of acrylamide (AM)/acrylic acid (AA) onto starch (St-g-pAA and St-g-p (AA-co-AM) was carried out using an orthogonal test method. The combined effects of different reaction conditions on the water absorbency of the graft copolymers were optimized through mathematical statistical methods of range and square variance analysis. The maximum water absorbency was obtained when the ratio of dried starch to distilled water was 1∶8 (w/w), the ratio of starch to monomer 1∶6 (w/w), the initiator concentration 4.40×10$^{−3}$ mol/L, the crosslinker concentration 10.86×10$^{−2}$ mol/L, and the basicity to AA 0.70 (mol/mol). Both the graft copolymers have an excellent water absorption capacity in distilled water and in 0.9 wt% NaCl solution. It was also found that in distilled water the water absorbency of St-g-pAA was higher than that of St-g-p(AA-co-AM), while in 0.9 wt% NaCl solution, the situation was just the reverse. The correlation between the water absorbency and the nature of the solution and the properties of the copolymers, which is related to the properties of the monomers, was discussed. The grafting of AA and AM onto starch was confirmed by the IR spectra of St-g-pAA and St-g-p (AA-co-AM).
Starting Page	83
Ending Page	87
Page Count	5
File Format	PDF
ISSN	10002413
Journal	Journal of Wuhan University of Technology-Mater. Sci. Ed.
Volume Number	21
Issue Number	2
e-ISSN	19930437
Language	English
Publisher	Wuhan University of Technology
Publisher Date	2005-01-01
Publisher Place	Wuhan
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	starch acrylic acid acrylamide graft copolymerization water absorbency orhogonal test Materials Science
Content Type	Text
Resource Type	Article
Subject	Materials Science

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

A study of the graft copolymerization of acrylic acid and acrylamide and their binary mixtures with some other vinyl monomers onto cellulose and its derivatives

Graft copolymerization of granular allyl starch with carboxyl-containing vinyl monomers for enhancing grafting efficiency

Graft copolymerization of vinyl monomers onto starch their characterization and degradation studies

Studies in the graft copolymerization of vinyl monomers onto starch cellulose and wool

Convenient synthetic method of starch/lactic acid graft copolymer catalyzed with sodium hydroxide

The optimized synthesis of starch-g-lactic acid copolymer with high grafting degree catalyzed by sulfuric acid

Development of Hydrogel Polyelectrolyte Membranes with Fixed Sulpho-Groups via Radical Copolymerization of Acrylic Monomers

Radical Copolymerization of Allyl and Vinyl Monomers Derived from 1,4-Benzoquinone with Acrylic Acid

Preparation of Poly(acrylic acid-acrylamide/starch) Composite and Its Adsorption Properties for Mercury (II)

The optimization of synthesizing graft copolymer of starch with vinyl monomers

Similar Documents

A study of the graft copolymerization of acrylic acid and acrylamide and their binary mixtures with some other vinyl monomers onto cellulose and its derivatives

Graft copolymerization of granular allyl starch with carboxyl-containing vinyl monomers for enhancing grafting efficiency

Graft copolymerization of vinyl monomers onto starch their characterization and degradation studies

Studies in the graft copolymerization of vinyl monomers onto starch cellulose and wool

Convenient synthetic method of starch/lactic acid graft copolymer catalyzed with sodium hydroxide

The optimized synthesis of starch-g-lactic acid copolymer with high grafting degree catalyzed by sulfuric acid

Development of Hydrogel Polyelectrolyte Membranes with Fixed Sulpho-Groups via Radical Copolymerization of Acrylic Monomers

Radical Copolymerization of Allyl and Vinyl Monomers Derived from 1,4-Benzoquinone with Acrylic Acid

Preparation of Poly(acrylic acid-acrylamide/starch) Composite and Its Adsorption Properties for Mercury (II)

The optimization of synthesizing graft copolymer of starch with vinyl monomers