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Salt effect on the phase transition behavior of thermo-sensitive polyamide

Content Provider	Springer Nature Link
Author	Lu, Lingbin Wang, Zhiyi Cao, Yang
Copyright Year	2012
Abstract	Phase transition behavior and influence of ions on the thermo-sensitive polyamide with polyethylene glycol as the main chain were studied in detail. By measuring the light transmission rates of polymer solutions, the change of its lower critical solution temperature (LCST) in the salt solution was investigated. It was found that a reversible phase transition of the polyamide occurred at the LCST and finished in a narrow temperature range. The LCST was associated with species of ions in salt solution. Anions had a great impact on the phase transition performance of the thermo-sensitive polyamide, while the cations had a slight influence on the phase transition. Different anions had different coagulation ability to ‘salt-out’ the polyamide. The order was: CO$_{3}$ $^{2−}$>SiO$_{3}$ $^{2−}$>HPO$_{4}$ $^{2−}$>OH$^{−}$>Cl$^{−}$>HCO$^{3−}$>HSO$^{3−}$>NO$^{2−}$>NO$^{3−}$.
Starting Page	285
Ending Page	289
Page Count	5
File Format	PDF
ISSN	10002413
Journal	Journal of Wuhan University of Technology-Mater. Sci. Ed.
Volume Number	27
Issue Number	2
e-ISSN	19930437
Language	English
Publisher	Wuhan University of Technology
Publisher Date	2012-04-12
Publisher Place	Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	temperature-sensitive polymer critical solution temperature salt effect phase transition behavior Materials Science
Content Type	Text
Resource Type	Article
Subject	Materials Science

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