NDLI: Anion reorientation in anhydrous Na$_{3}$PO$_{4}$ during the phase transformation

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Anion reorientation in anhydrous Na$_{3}$PO$_{4}$ during the phase transformation

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Anion reorientation in anhydrous Na$_{3}$PO$_{4}$ during the phase transformation

Content Provider	Springer Nature Link
Author	Raje, G. Kalaiselvi, B. J. Shanmukaraj, D. Sridarane, R. Palanivel, B. Murugan, Ramaswamy
Copyright Year	2004
Abstract	The transport phenomena in alkali-metal super ionic conductors based on Na$_{3}$PO$_{4}$ structure are of particular interest due to their potential technological application. Differential thermal analysis (DTA), differential scanning calorimetry (DSC), Raman spectroscopy and temperature dependent electrical conductivity measurements were carried out to probe the nature of the phase transformation involved in anhydrous Na$_{3}$PO$_{4}$. The changes in spectral profile of the v$_{3}$ mode and the line width of v$_{1}$ mode of PO 4 3− observed in the temperature interval from 331 to 345 °C revealed the high degree of disorder nature during the α-γNa$_{3}$PO$_{4}$ phase transformation.
Starting Page	263
Ending Page	267
Page Count	5
File Format	PDF
ISSN	09477047
Journal	Ionics
Volume Number	10
Issue Number	3-4
e-ISSN	18620760
Language	English
Publisher	Springer-Verlag
Publisher Date	2004-01-01
Publisher Place	Berlin, Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Biomedicine general Analytical Chemistry Physical Chemistry Electrochemistry Optical and Electronic Materials
Content Type	Text
Resource Type	Article
Subject	Physics and Astronomy Engineering Materials Science Chemical Engineering

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