NDLI: An experimental and theoretical study on the structure and photoactivity of XFe$_{2}$O$_{4}$ (X = Mn, Fe, Ni, Co, and Zn) structures

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An experimental and theoretical study on the structure and photoactivity of XFe$_{2}$O$_{4}$ (X = Mn, Fe, Ni, Co, and Zn) structures

Content Provider	Springer Nature Link
Author	Padervand, M. Vossoughi, M. Yousefi, H. Salari, H. Gholami, M. R.
Copyright Year	2014
Abstract	XFe$_{2}$O$_{4}$ magnetic nanoparticles (X = Mn, Fe, Co, Ni, and Zn) were prepared by using two methods: coprecipitation and hydrothermal. The synthesized nanoparticles were compared according to the separation in an external magnetic field and finally, the hydrothermal method was specified as a better synthesis method. The magnetic nanoparticles were characterized by physico-chemical analysis methods such as Vibrating Sample Magnetometer (VSM), X-ray diffraction (XRD), Fourier Transform Infrared spectroscopy (FTIR), nitrogen adsorption-adsorption isotherm and Transmission Electron Microscopy (TEM). Magnetic properties of synthesized nanoparticles were studied by ab-initio theoretical methods to confirm and compare with the experimental results. According to the VSM analysis, all of magnetic nanoparticles had good magnetization while CoFe$_{2}$O$_{4}$ nanoparticles showed the ferromagnetic behavior. The magnetic properties of XFe$_{2}$O$_{4}$ configurations were studied using Density Functional Theory ab-initio method. The theoretical results were consistent with experimental magnetizations in the absence of external field. Finally, the photocatalytic behavior of prepared samples was investigated in the presence of oxone as an accelerated agent for degradation of an azo dye.
Starting Page	2451
Ending Page	2461
Page Count	11
File Format	PDF
ISSN	00360244
Journal	Russian Journal of Physical Chemistry
Volume Number	88
Issue Number	13
e-ISSN	1531863X
Language	English
Publisher	Pleiades Publishing
Publisher Date	2014-11-06
Publisher Place	Moscow
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	magnetic nanoparticles XFe$_{2}$O$_{4}$ organic template ab initio calculation oxone Physical Chemistry
Content Type	Text
Resource Type	Article
Subject	Physical and Theoretical Chemistry

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