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Primary stage of the reaction between ozone and chloride ions in aqueous solution: Can chloride ion oxidation by ozone proceed via electron transfer mechanism?

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Primary stage of the reaction between ozone and chloride ions in aqueous solution: Can chloride ion oxidation by ozone proceed via electron transfer mechanism?

Content Provider	Springer Nature Link
Author	Levav, A. V. Antipenko, E. E. Lunin, V. V.
Copyright Year	2012
Abstract	It is found that chloride-ion oxidation by ozone via electron transfer mechanism does not occur due to its extremely high endoergicity and negligibly low rate. It is concluded that all processes supposedly associated with this reaction, particularly ozone decomposition in sodium chloride solution initiated by Cl$^{·}$ atoms, do not take place either. It is shown that experimental data on the products and kinetic regularities of the interaction of O$_{3}$ with Cl$^{−}$ contradict the assumption that the electron transfer reaction is its primary stage. In fact, chloride-ion oxidation by ozone proceeds via the mechanism of oxygen atom transfer. It is noted that in order to estimate the possibility of using an ozonated physiological saline in medicine, the formation of chloride-ion oxidation products and ozonation byproducts must be taken into account.
Starting Page	584
Ending Page	589
Page Count	6
File Format	PDF
ISSN	00360244
Journal	Russian Journal of Physical Chemistry
Volume Number	86
Issue Number	4
e-ISSN	1531863X
Language	English
Publisher	SP MAIK Nauka/Interperiodica
Publisher Date	2012-02-27
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	ozone chloride-ion electron transfer reaction physiological saline chemical reaction kinetics Physical Chemistry
Content Type	Text
Resource Type	Article
Subject	Physical and Theoretical Chemistry

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Primary stage of the reaction between ozone and chloride ions in aqueous solution: Oxidation of chloride ions with ozone through the mechanism of oxygen atom transfer

Erratum to: “Primary stage of the reaction between ozone and chloride ions in aqueous solution: Oxidation of chloride ions with ozone through the mechanism of oxygen atom transfer”

Erratum to: “Primary stage of the reaction between ozone and chloride ions in aqueous solution: Oxidation of chloride ions with ozone through the mechanism of oxygen atom transfer”

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Primary stage of the reaction between ozone and chloride ions in aqueous solution: Can chloride ion oxidation by ozone proceed via electron transfer mechanism?

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Primary stage of the reaction between ozone and chloride ions in aqueous solution: Oxidation of chloride ions with ozone through the mechanism of oxygen atom transfer

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