NDLI: Synthesis and proton conductivity of adsorption-saturated and solvated porous hydroxyethylated cyclam layers on the surface of PVC-coated cellulose fabric

Content Provider	Springer Nature Link
Author	Fridman, A. Ya. Tsivadze, A. Yu. Morozova, E. M. Sokolova, N. P. Voloshchuk, A. M. Bardyshev, I. I. Gorbuv, A. M. Polyakova, I. Ya. Titova, V. N. Yavich, A. A. Shapokhina, O. P. Petrova, N. V. Averin, A. A.
Copyright Year	2014
Abstract	Porous layers of associates of adsorption-saturated and benzene- and hexane-solvated chloride and sulfate of hydroxyethylated cyclams with acid aqua complexes were synthesized on the surface of PVC-coated cellulose fabric. The porous structure of the layers includes a system of internal pores connected with the external pores via the diamine rings of the common walls of the hydroxyethylated cyclam nets; the internal pores are filled with the associates; the solvent molecules are adsorbed on the developed surface of the layers or solvate it. The H$^{+}$ motion rate in a layer placed in solvent vapors or liquid solvents was measured; the layers were found to be nonlinear H$^{+}$ conductors. The potential of H$^{+}$ transition from the acid solution into the layer, the H$^{+}$ mobility constant, and the field variation constant of the H$^{+}$ mobility of the layer depend on the layer composition. The adsorption and solvation are accompanied by the formation of host-guest molecular complexes between the diamine rings of the cyclam nets and the benzene or hexane molecules, affecting the resistance of the associates to the incorporation of H$^{+}$ ions and the H$^{+}$ mobility in the associates.
Starting Page	1413
Ending Page	1418
Page Count	6
File Format	PDF
ISSN	00360244
Journal	Russian Journal of Physical Chemistry
Volume Number	88
Issue Number	8
e-ISSN	1531863X
Language	English
Publisher	Pleiades Publishing
Publisher Date	2014-07-18
Publisher Place	Moscow
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	synthesis layer porosity associate acid cyclam proton conductivity complex Physical Chemistry
Content Type	Text
Resource Type	Article
Subject	Physical and Theoretical Chemistry

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