NDLI: Lower size boundary for the applicability of thermodynamics

Content Provider	Springer Nature Link
Author	Tovbin, Yu. K.
Copyright Year	2012
Abstract	The problem of the lower boundary of the intrinsic linear size of the range in which the thermodynamic approach is applicable is considered. It is established that a natural constraint of any thermodynamic approach is the discrete structure of a substance at the atomic-molecular level. It is shown that with a reduction in the size of a substance, the fraction of surface particles compared to their total amount grows and spontaneous density fluctuations increase. The molecular theory of density fluctuation in small systems is discussed. Drop radii below which thermodynamic approaches cannot be used, and for which thermodynamic approaches can be used when both the discreteness of a substance and the contributions from spontaneous fluctuations can be ignored, are estimated. The consequences of the molecular theory of curved vapor-liquid interfaces are examined within the lattice gas model for spherical drops in the vapor phase. The limitations and conditions for considering corrections for density fluctuations in macrophases are discussed.
Starting Page	1356
Ending Page	1369
Page Count	14
File Format	PDF
ISSN	00360244
Journal	Russian Journal of Physical Chemistry
Volume Number	86
Issue Number	9
e-ISSN	1531863X
Language	English
Publisher	SP MAIK Nauka/Interperiodica
Publisher Date	2012-08-06
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	drop radius thermodynamics discreteness of substance lattice gas model macrophase Physical Chemistry
Content Type	Text
Resource Type	Article
Subject	Physical and Theoretical Chemistry

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