NDLI: MOF-derived hollow NiO–ZnO composite micropolyhedra and their application in catalytic thermal decomposition of ammonium perchlorate

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MOF-derived hollow NiO–ZnO composite micropolyhedra and their application in catalytic thermal decomposition of ammonium perchlorate

Content Provider	Springer Nature Link
Author	Yang, Ji Min
Copyright Year	2017
Abstract	Ni(II)-doped Zn-based coordination polymer particles (Ni(II)-doped Zn-CPPs) with controllable shape and size were successfully synthesized by solvothermal method, which further transformed to porous ZnO–NiO composite micropolyhedra without significant alterations in shape by calcination in air. Those products were characterized by powder X-ray diffraction (XRD), field emission scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), infrared spectroscopy (IR) and gas adsorption measurements. The catalytic activity of ZnO–NiO composites for the thermal decomposition of ammonium perchlorate (AP) was investigated. The result shows that all ZnO–NiO composites efficiently catalyzed the thermal decomposition of AP, and NiO–ZnO composite hollow octahedrons have the highest catalytic efficiency compared with that of most materials reported to now, indicating that porous ZnO–NiO composite micropolyhedra could be a promising candidate material for application in AP-based propellant.
Starting Page	1214
Ending Page	1220
Page Count	7
File Format	PDF
ISSN	00360244
Journal	Russian Journal of Physical Chemistry
Volume Number	91
Issue Number	7
e-ISSN	1531863X
Language	English
Publisher	Pleiades Publishing
Publisher Date	2017-06-15
Publisher Place	Moscow
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	coordination polymer hollow structure catalytic activity shape AP Physical Chemistry
Content Type	Text
Resource Type	Article
Subject	Physical and Theoretical Chemistry

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