NDLI: Synthesis, structure, and physicochemical properties of K[VO$_{2}$(SeO$_{4}$)(H$_{2}$O)] and K[VO$_{2}$(SeO$_{4}$)(H$_{2}$O)$_{2}$]

Content Provider	Springer Nature Link
Author	Tyutyunnik, A. P. Krasil’nikov, V. N. Berger, I. F. Zubkov, V. G. Perelyaeva, L. A. Baklava, I. V.
Copyright Year	2011
Abstract	The vanadium(V) complexes K[VO$_{2}$(SeO$_{4}$)(H$_{2}$O)] and K[VO$_{2}$(SeO$_{4}$)(H$_{2}$O)$_{2}$] · H$_{2}$O were synthesized using original procedures; their physicochemical properties were studied, and the crystal structure was determined on the basis of X-ray diffraction and neutron diffraction data. The structure of K[VO$_{2}$(SeO$_{4}$)(H$_{2}$O)$_{2}$] · H$_{2}$O is composed of VO$_{6}$ octahedra connected to form infinite chains by bridging SeO$_{4}$ tetrahedra. Each VO$_{6}$ tetrahedron has short terminal V-O bonds forming the bent dioxovanadium group VO 2 + The unit cell parameters of K[VO$_{2}$(SeO$_{4}$)(H$_{2}$O)$_{2}$] · H$_{2}$O are a = 6.4045(1) Å, b = 9.9721(2) Å, c = 6.6104(1) Å, β = 107.183(1)°, V = 403.34 Å$^{3}$, Z = 2, monoclinic system, space group P2$_{1}$. The complex K[VO$_{2}$(SeO$_{4}$)(H$_{2}$O)] forms a two-dimensional layered structure composed of highly distorted VO$_{6}$ octahedra having two short terminal V-O bonds and SeO$_{4}$ groups coordinated simultaneously by three vanadium atoms. This compound crystallizes in the monoclinic system (space group P2$_{1}$/c): a = 7.3783(1) Å, b = 10.5550(2) Å, c = 10.3460(2) Å, β = 131.625(1)°, V = 602.894(5) Å$^{3}$, Z= 4. The vibrational spectra of the studied compounds are fully consistent with their structural features.
Starting Page	1168
Ending Page	1177
Page Count	10
File Format	PDF
ISSN	00360236
Journal	Russian Journal of Inorganic Chemistry
Volume Number	56
Issue Number	8
e-ISSN	15318613
Language	English
Publisher	SP MAIK Nauka/Interperiodica
Publisher Date	2011-08-16
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Inorganic Chemistry
Content Type	Text
Resource Type	Article
Subject	Physical and Theoretical Chemistry Materials Science Inorganic Chemistry

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