NDLI: Membrane separation of gaseous C$_{1}$-C$

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Membrane separation of gaseous C$_{1}$-C$_{4}$ alkanes

Content Provider	Springer Nature Link
Author	Grinevich, Yu. Starannikova, L. Yampol’skii, Yu. Gringol’ts, M. Finkel’shtein, E.
Copyright Year	2011
Abstract	The separation of various gaseous hydrocarbons with the aid of polymer membranes is considered; attention is focused on the separation of gaseous C$_{1}$–C$_{4}$ alkanes, which are the components of natural gas and associated petroleum gases. It is noted that a practically important property of membrane materials is the thermodynamic selectivity of a membrane, which makes it possible to enrich a permeate with heavier alkanes. Up to this point, polyacetylenes exhibited the best transport parameters for the solution of this problem. The second experimental section of this paper describes a study of the separation of CH$_{4}$ + C$_{4}$H$_{10}$ binary mixtures on films based on additive poly[3-(trimethylsilyl)tricyclononene-7]. It is demonstrated that this highly permeable saturated glassy polymer exhibits thermodynamic selectivity in experiments with both the individual gases (CH$_{4}$ and C$_{4}$H$_{10}$) and their mixtures and provides fivefold butane enrichment of a permeate. The test polymer and others additive Si-containing norbornene polymers are of interest as membrane materials for the separation of hydrocarbon gases.
Starting Page	585
Ending Page	594
Page Count	10
File Format	PDF
ISSN	09655441
Journal	Petroleum Chemistry
Volume Number	51
Issue Number	8
e-ISSN	15556239
Language	English
Publisher	SP MAIK Nauka/Interperiodica
Publisher Date	2012-01-05
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Industrial Chemistry/Chemical Engineering
Content Type	Text
Resource Type	Article
Subject	Chemistry Geochemistry and Petrology Fuel Technology Chemical Engineering Energy Engineering and Power Technology

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