NDLI: Synthesis and structural study on (1E,2E,1′E,2′E)-3,3′-bis[(4-bromophenyl)-3,3′-(4-methy-1,2-phenylene diimine)] acetaldehyde dioxime: A combined experimental and theoretical study

Content Provider	Springer Nature Link
Author	Topal, T. Kart, H. H. Tunay Taşlı, P. Karapınar, E.
Copyright Year	2015
Abstract	Tetradentate (1E,2E,1′E,2′E)-3,3′-bis[(4-bromophenyl)-3,3′-(4-methy-1,2-phenylene diimine)] acetaldehyde dioxime which possess N$_{4}$ donor sets derived from the condensation of isonitroso-p-bromoacetophenone and 3,4-diaminotoluene are synthesized and characterized. The characterization of tetradentate Schiff base ligand has been deduced from LC-MS, FTIR, $^{13}$C and $^{1}$H NMR spectra and elemental analysis. Furthermore, the molecular geometry, infrared and NMR spectra of the title molecule in the ground state have been calculated by using the quantum chemical computational methods such as density functional theory (DFT) and ab initio Hartree-Fock (HF) methods with the 6–31G(d) and 6–311G(d) basis sets. The computed bond lengths and bond angles by using the both methods show the good agreement with each other. Moreover, the vibrational frequencies have been calculated and the scaled values have been compared with the experimental FTIR spectroscopic data. Assignments of the vibrational modes are made on the basis of potential energy distribution (PED) calculated from by using VEDA program. The correlations between the observed and calculated frequencies are in good agreement with each other as well as the correlation of the NMR data.
Starting Page	865
Ending Page	881
Page Count	17
File Format	PDF
ISSN	0030400X
Journal	Optics and Spectroscopy
Volume Number	118
Issue Number	6
e-ISSN	15626911
Language	English
Publisher	Pleiades Publishing
Publisher Date	2015-06-26
Publisher Place	Moscow
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Optics, Optoelectronics, Plasmonics and Optical Devices
Content Type	Text
Resource Type	Article
Subject	Atomic and Molecular Physics, and Optics Electronic, Optical and Magnetic Materials

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Synthesis and Characterization of Tetraoxime Ligand, Bis-[(2E,3E,2´E)-3,3´-(1,2-Phenylene-Dinitrilo)dibutan-2-One Dioxime] and Its Dinuclear and Tetranuclear Copper(II)/Nickel(II) Complexes

Synthesis and Characterization of Tetraoxime Ligand, Bis-[(2E,3E,2´E)-3,3´-(1,2-Phenylene-Dinitrilo)dibutan-2-One Dioxime] and Its Dinuclear and Tetranuclear Copper(II)/Nickel(II) Complexes

Synthesis and Characterization of Tetraoxime Ligand, Bis-[(2E,3E,2´E)-3,3´-(1,2-Phenylene-Dinitrilo)dibutan-2-One Dioxime] and Its Dinuclear and Tetranuclear Copper(II)/Nickel(II) Complexes

Thermal, Electrical, and Optical Properties of Synthesized (1E, 2E)-(4-bromophenyl)(hydroxyimino)acetaldehyde Oxime Complexes

Thermal, Electrical, and Optical Properties of Synthesized (1E, 2E)-(4-bromophenyl)(hydroxyimino)acetaldehyde Oxime Complexes

Photonics of zinc complexes of 3,3′-bis(dipyrrolylmethenes)

Erratum to: “Photonics of Zinc Complexes of 3,3′-Bis(dipyrrolylmethenes)”

(1E,2E)-1,2-Bis(3-bromo-4-methoxybenzylidene)hydrazine

Validated spectrophotometric method for the determination, spectroscopic characterization and thermal structural analysis of duloxetine with 1,2-naphthoquinone-4-sulphonate

Synthesis and structural study on (1E,2E,1′E,2′E)-3,3′-bis[(4-bromophenyl)-3,3′-(4-methy-1,2-phenylene diimine)] acetaldehyde dioxime: A combined experimental and theoretical study

Similar Documents

Synthesis and Characterization of Tetraoxime Ligand, Bis-[(2E,3E,2´E)-3,3´-(1,2-Phenylene-Dinitrilo)dibutan-2-One Dioxime] and Its Dinuclear and Tetranuclear Copper(II)/Nickel(II) Complexes

Synthesis and Characterization of Tetraoxime Ligand, Bis-[(2E,3E,2´E)-3,3´-(1,2-Phenylene-Dinitrilo)dibutan-2-One Dioxime] and Its Dinuclear and Tetranuclear Copper(II)/Nickel(II) Complexes

Synthesis and Characterization of Tetraoxime Ligand, Bis-[(2E,3E,2´E)-3,3´-(1,2-Phenylene-Dinitrilo)dibutan-2-One Dioxime] and Its Dinuclear and Tetranuclear Copper(II)/Nickel(II) Complexes

Thermal, Electrical, and Optical Properties of Synthesized (1E, 2E)-(4-bromophenyl)(hydroxyimino)acetaldehyde Oxime Complexes

Thermal, Electrical, and Optical Properties of Synthesized (1E, 2E)-(4-bromophenyl)(hydroxyimino)acetaldehyde Oxime Complexes

Photonics of zinc complexes of 3,3′-bis(dipyrrolylmethenes)

Erratum to: “Photonics of Zinc Complexes of 3,3′-Bis(dipyrrolylmethenes)”

(1E,2E)-1,2-Bis(3-bromo-4-methoxybenzylidene)hydrazine

Validated spectrophotometric method for the determination, spectroscopic characterization and thermal structural analysis of duloxetine with 1,2-naphthoquinone-4-sulphonate

Synthesis and structural study on (1E,2E,1′E,2′E)-3,3′-bis[(4-bromophenyl)-3,3′-(4-methy-1,2-phenylene diimine)] acetaldehyde dioxime: A combined experimental and theoretical study