NDLI: Synthesis, photophysical properties and TD-DFT calculation of four two-photon absorbing triphenylamine derivatives

Content Provider	Springer Nature Link
Author	Kong, Lin Yang, JiaXiang Zhou, HongPing Li, ShengLi Hao, FuYing Zhang, Qiong Tu, YuLong Wu, JieYing Xue, ZhaoMing Tian, YuPeng
Copyright Year	2012
Abstract	In this study, linear absorption, single-photon excited fluorescence, fluorescence quantum yields, fluorescence lifetime and two-photon excited fluorescence of a series of triphenylamine derivatives (L1, L2, L3 and L4) have been measured. L1 and L3 are D-π-A type dyes, while L2 and L4 are D-π-D-π-A type dyes (D = donor, A = acceptor). The investigated compounds consist of triphenylamine-bearing donor-substituted and/or systematically extended π-conjugated length, which are designed to gain insight into the effect of the ethoxyl unit and π-linkage length on the linear and nonlinear optical properties. The influence of solvent polarity on the photophysical properties was investigated. Employing time-dependent density functional theory (TD-DFT) calculations, the structure-property relationships are discussed.
Starting Page	106
Ending Page	116
Page Count	11
File Format	PDF
ISSN	16747291
Journal	Science in China Series B: Chemistry
Volume Number	56
Issue Number	1
e-ISSN	18691870
Language	English
Publisher	SP Science China Press
Publisher Date	2012-12-21
Publisher Place	Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	triphenylamine derivatives optical properties structure-property relationship TD-DFT calculation Chemistry/Food Science
Content Type	Text
Resource Type	Article
Subject	Chemistry

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