NDLI: Facile synthesis of dendrimer-like star-branched poly(isopropylacrylamide) via combination of click chemistry and atom transfer radical polymerization

Please wait, while we are loading the content...

Facile synthesis of dendrimer-like star-branched poly(isopropylacrylamide) via combination of click chemistry and atom transfer radical polymerization

Applications of synchrotron-based X-ray techniques in environmental science

Supramolecularly assembled water layers stabilized by sebacic anions in complexes of Zn(II) and Co(II)

Total synthesis of lespedezavirgatol

Effect of the pore size of Co/SBA-15 isomorphically substituted with zirconium on its catalytic performance in Fischer-Tropsch synthesis

Mediated electrochemistry of dimethyl sulfoxide reductase promoted by carbon nanotubes

Prediction of the thermodynamic properties of 1-alkyl-3-methylimidazolium lactate ionic liquids [C$_{n}$mim][Lact] (n = 2, 3, 4, 5, and 6) by parachor

Theoretical studies of the transport property of oligosilane

Disposable amperometric biosensors based on xanthine oxidase immobilized in the Prussian blue modified screen-printed three-electrode system

Synthesis of molecularly imprinted polymers for the application of selective clean-up vinblastine from Catharanthus roseus extract

Identification of secondary organic aerosols based on aerosol mass spectrometry

Temperature-controlled ionic liquid dispersive liquid phase microextraction combined with ultra-high-pressure liquid chromatography for the rapid determination of triclosan, triclocarban and methyl-triclosan in aqueous samples

Effects of bacterially produced precipitates on the metabolism of sulfate reducing bacteria during the bio-treatment process of copper-containing wastewater

Prediction of daytime variations of HO$_{2}$ radical concentrations in the marine boundary layer using BP network

Kinetic studies of gas hydrate formation with low-dosage hydrate inhibitors

Eu(III) adsorption on rutile: Batch experiments and modeling

Heterogeneous reaction of SO$_{2}$ on TiO$_{2}$ particles

Heterogeneous reaction of formaldehyde on the surface of TiO$_{2}$ particles

Heterogeneous reaction of NO$_{2}$ with sea salt particles

Heterogeneous reactions of gaseous methanesulfonic acid with calcium carbonate and kaolinite particles

Focus on polymer chemistry papers in Science in China Series B: Chemistry of the year 2009

Science in China Series B: Chemistry : Volume 53, Issue 11, November 2010

Science in China Series B: Chemistry : Volume 53, Issue 10, October 2010

Science in China Series B: Chemistry : Volume 53, Issue 9, September 2010

Science in China Series B: Chemistry : Volume 53, Issue 8, August 2010

Science in China Series B: Chemistry : Volume 53, Issue 7, July 2010

Science in China Series B: Chemistry : Volume 53, Issue 6, June 2010

Science in China Series B: Chemistry : Volume 53, Issue 5, May 2010

Science in China Series B: Chemistry : Volume 53, Issue 4, April 2010

Science in China Series B: Chemistry : Volume 53, Issue 3, March 2010

Science in China Series B: Chemistry : Volume 53, Issue 2, February 2010

Science in China Series B: Chemistry : Volume 53, Issue 1, January 2010

Science in China Series B: Chemistry : Volume 52

Science in China Series B: Chemistry : Volume 51

Science in China Series B: Chemistry : Volume 50

Science in China Series B: Chemistry : Volume 49

Science in China Series B: Chemistry : Volume 48

Science in China Series B: Chemistry : Volume 47

Science in China Series B: Chemistry : Volume 46

Science in China Series B: Chemistry : Volume 45

Science in China Series B: Chemistry : Volume 44

Science in China Series B: Chemistry : Volume 43

Science in China Series B: Chemistry : Volume 42

Science in China Series B: Chemistry : Volume 41

Science in China Series B: Chemistry : Volume 40

Facile synthesis of dendrimer-like star-branched poly(isopropylacrylamide) via combination of click chemistry and atom transfer radical polymerization

Content Provider	Springer Nature Link
Author	Wan, XueJuan Xu, Jian Liu, ShiYong
Copyright Year	2010
Abstract	We report a facile synthesis method of dendrimer-like star-branched poly(N-isopropylacrylamide) (PNIPAM) via the combination of click chemistry and atom transfer radical polymerization (ATRP) by employing the arm-first approach. First, the α-azido-ω-chloro-heterodifunctionalized building block, N $_{3}$-PNIPAM-Cl (G0-Cl), was synthesized via ATRP by 3-azidopropyl 2-chloropropionate as the initiator. Taking advantage of click chemistry, the first generation (G1) of dendrimer-like star-branched PNIPAM, G1-(Cl)$_{3}$, was facilely prepared via the click coupling reaction between G0-Cl and tripropargylamine. For the construction of second generation (G2) dendrimer-like star-branched PNIPAM, G2-(Cl)$_{6}$, terminal chloride moieties of G1-(Cl)$_{3}$ were first converted to azide, and then reacted with excess tripropargylamine to give G1-(alkynyl)$_{6}$; G2-(Cl)$_{6}$ was subsequently prepared via click reaction between G1-(alkynyl)$_{6}$ and G0-Cl. Gel permeation chromatography (GPC) and matrix-assisted laser desorption/ionization time-of-flight (MALDI-TOF) mass spectrometry were employed to confirm the successful construction of dendrimer-like star-branched polymers. The unique thermal phase transition behavior of this dendrimer-like star-branched polymer in aqueous solutions was further investigated by turbidimetry and micro-differential scanning calorimetry (Micro-DSC).
Starting Page	2520
Ending Page	2527
Page Count	8
File Format	PDF
ISSN	16747291
Journal	Science in China Series B: Chemistry
Volume Number	53
Issue Number	12
e-ISSN	18691870
Language	English
Publisher	SP Science China Press
Publisher Date	2010-12-12
Publisher Place	Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	dendrimer-like branched ATRP click chemistry Chemistry/Food Science
Content Type	Text
Resource Type	Article
Subject	Chemistry

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Synthesis and characterization of poly(2-ethylhexyl acrylate) prepared via atom transfer radical polymerization, reverse atom transfer radical polymerization and radical polymerization

Preparation of poly(N-isopropylacrylamide) brush grafted silica particles via surface-initiated atom transfer radical polymerization used for aqueous chromatography

Synthesis of A3B3-type polystyrene–poly(methyl methacrylate) miktoarm star polymers via combination of stable free radical and atom transfer radical polymerization routes

Synthesis and characterization of PSt-b-PVAc diblock copolymers via combination of atom transfer radical polymerization and cobalt-mediated radical polymerization

Synthesis and characterization of AB2-type star polymers via combination of ATRP and click chemistry

Synthesis of star-shaped poly(N-isopropylacrylamide) via atom transfer radical polymerization and its photocatalytic oxidation of Rhodamine B

End-Functionalized Poly(N-isopropylacrylamide) with d-Glucosamine through Different Initiator from C-1 and C-2 Positions via Atom Transfer Radical Polymerization

A new strategy for the preparation of multiarm star-shaped polystyrene via a combination of atom transfer radical polymerization and cationic ring-opening polymerization

Preparation of star block co-polymers by combination of cationic ring opening polymerization and atom transfer radical polymerization

Facile synthesis of dendrimer-like star-branched poly(isopropylacrylamide) via combination of click chemistry and atom transfer radical polymerization

Similar Documents

Synthesis and characterization of poly(2-ethylhexyl acrylate) prepared via atom transfer radical polymerization, reverse atom transfer radical polymerization and radical polymerization

Preparation of poly(N-isopropylacrylamide) brush grafted silica particles via surface-initiated atom transfer radical polymerization used for aqueous chromatography

Synthesis of A3B3-type polystyrene–poly(methyl methacrylate) miktoarm star polymers via combination of stable free radical and atom transfer radical polymerization routes

Synthesis and characterization of PSt-b-PVAc diblock copolymers via combination of atom transfer radical polymerization and cobalt-mediated radical polymerization

Synthesis and characterization of AB2-type star polymers via combination of ATRP and click chemistry

Synthesis of star-shaped poly(N-isopropylacrylamide) via atom transfer radical polymerization and its photocatalytic oxidation of Rhodamine B

End-Functionalized Poly(N-isopropylacrylamide) with d-Glucosamine through Different Initiator from C-1 and C-2 Positions via Atom Transfer Radical Polymerization

A new strategy for the preparation of multiarm star-shaped polystyrene via a combination of atom transfer radical polymerization and cationic ring-opening polymerization

Preparation of star block co-polymers by combination of cationic ring opening polymerization and atom transfer radical polymerization

Facile synthesis of dendrimer-like star-branched poly(isopropylacrylamide) via combination of click chemistry and atom transfer radical polymerization