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| Content Provider | Springer Nature Link |
|---|---|
| Author | Zhang, Jiaxing Wang, Guowei |
| Copyright Year | 2015 |
| Abstract | Because glycidyl (Gly) contains an epoxy and an active hydroxyl group, the Gly unit is difficult to introduce into certain polymeric chains in a controlled manner and usually yields hyperbranched polyglycidyl. Alternatively, the monomer 1-ethoxyethyl glycidyl ether (EEGE), derived from Gly and ethyl vinyl ether, has shown potential for application in polymer chemistry, and homopolymerization of this monomer directly produces linear poly(1-ethoxyethyl glycidyl ether) and further yields linear polyglycidyl. In this review, the initiation system of the EEGE monomer is first discussed in terms of chain transfer to monomers in ring-opening polymerization of epoxides with substituent groups. Then, random copolymerization of EEGE with other epoxides is considered. In addition, because the EEGE units on polymers can be transferred to Gly units and further used to construct copolymers with complicated architectures, the applications of EEGE monomers to block, graft, and hyperbranched copolymers are reviewed. Finally, the synthesis of main chain and terminal functional polyethers by transforming the hydroxyl groups at the polymer end or on the main chain into certain functional groups are also discussed. Chemistry based on EEGE has been proved to be an efficient, versatile route to constructing copolymers containing Gly units and ultimately yielding the target properties and applications. |
| Starting Page | 1674 |
| Ending Page | 1694 |
| Page Count | 21 |
| File Format | |
| ISSN | 16747291 |
| Journal | Science in China Series B: Chemistry |
| Volume Number | 58 |
| Issue Number | 11 |
| e-ISSN | 18691870 |
| Language | English |
| Publisher | Science China Press |
| Publisher Date | 2015-08-03 |
| Publisher Place | Beijing |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | linear polyglycidyl (LPG) poly(1-ethoxyethyl glycidyl ether) (PEEGE) block polymer graft polymer hyper-branched polymer Chemistry/Food Science |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry |
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