NDLI: Reaction dynamics and statistical theory for the growth of hydrogen bonding clusters

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Reaction dynamics and statistical theory for the growth of hydrogen bonding clusters

Content Provider	Springer Nature Link
Author	Wang, Haijun Ba, Xinwu Zhao, Min
Copyright Year	2002
Abstract	The similarities between the formation of hydrogen bonds and polycondensation reactions are stated from the statistical viewpoint, and then taking the hydrogen bonding system of A $_{ a }$ D $_{ d }$ type as an example, the growing process of hydrogen bonding clusters is investigated in terms of the theory of reaction dynamics and statistical theory for polymeric reactions. The two methods lead to the same conclusions, stating that the statistical theory for polymerization is applicable to the hydrogen bonding systems. Based on this consideration, the explicit relationship between the conversions of proton-donors and proton-acceptors and the Gibbs free energy of the system under study is given. Furthermore, the sol-gel phase transition is predicted to take place in some hydrogen bonding systems, and the corresponding generalized scaling laws describing this kind of phase transition are obtained.
Starting Page	113
Ending Page	121
Page Count	9
File Format	PDF
ISSN	10069291
Journal	Science in China Series B: Chemistry
Volume Number	45
Issue Number	2
e-ISSN	18622771
Language	English
Publisher	Science in China Press
Publisher Date	2002-01-01
Publisher Place	Beijing
Access Restriction	Subscribed
Subject Keyword	hydrogen bonding cluster reaction dynamics sol-gel phase transition scaling law Chemistry/Food Science
Content Type	Text
Resource Type	Article
Subject	Chemistry

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