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| Content Provider | Springer Nature Link |
|---|---|
| Author | Sidoli, Pauline Baran, Nicole Angulo Jaramillo, Rafael |
| Copyright Year | 2015 |
| Abstract | Adsorption of the herbicide glyphosate and its main metabolite AMPA (aminomethylphosphonic acid) was investigated on 17 different agricultural soils. Batch equilibration adsorption data are shown by Freundlich adsorption isotherms. Glyphosate adsorption is clearly affected by equilibration concentrations, but the nonlinear AMPA adsorption isotherms indicate saturation of the adsorption sites with increasing equilibrium concentrations. pH$_{CaCl2}$ (i.e. experimental pH) is the major parameter governing glyphosate and AMPA adsorption in soils. However, considering pH$_{CaCl2}$ values, available phosphate amount, and amorphous iron and aluminium oxide contents by using a nonlinear multiple regression equation, obtains the most accurate and powerful pedotransfer rule for predicting the adsorption constants for these two molecules. As amorphous iron and aluminium oxide contents in soil are not systematically determined, we also propose a pedotransfer rule with two variables—pH$_{CaCl2}$ values and available phosphate amount—that remains acceptable for both molecules. Moreover, the use of the commonly measured pH$_{water}$ or pH$_{KCl}$ values gives less accurate results compared to pH$_{CaCl2}$ measurements. To our knowledge, this study is the first AMPA adsorption characterization for a significant number of temperate climate soils. |
| Starting Page | 5733 |
| Ending Page | 5742 |
| Page Count | 10 |
| File Format | |
| ISSN | 09441344 |
| Journal | Environmental Science and Pollution Research |
| Volume Number | 23 |
| Issue Number | 6 |
| e-ISSN | 16147499 |
| Language | English |
| Publisher | Springer Berlin Heidelberg |
| Publisher Date | 2015-11-19 |
| Publisher Place | Berlin, Heidelberg |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Glyphosate AMPA Sorption Nonlinear multiple regression Chromic cambisol Environment Environmental Chemistry Ecotoxicology Environmental Health Atmospheric Protection/Air Quality Control/Air Pollution Waste Water Technology Water Pollution Control Water Management Aquatic Pollution |
| Content Type | Text |
| Resource Type | Article |
| Subject | Environmental Chemistry Health, Toxicology and Mutagenesis Pollution Medicine |
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