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| Content Provider | Springer Nature Link |
|---|---|
| Author | Avila, Anna Molowny Horas, Roberto Gime, Benjamín S. Peñuelas, Josep |
| Copyright Year | 2009 |
| Abstract | Nitrogen emissions have grown in Spain during the last 15 years. As precipitation scavenges gases and aerosols from the atmosphere, an effect on rainwater concentrations can be expected. However, time-series studies on wet N concentrations in the Iberian Peninsula are very scarce. This paper aims to fill this gap by analysing weekly rainfall N concentrations at a set of rural sites in Catalonia (NE Spain) from 1995/1996 to 2007 and a forest site monitored from 1983 to 2007. The sites encompass a range of rural environments and climate conditions, from the inland pre-Pyrenees (Sort) to the Mediterranean coast (Begur) and from north (Sort and Begur) to central (Palautordera and La Castanya) and south Catalonia (La Senia). We found a 1-year cycle for concentrations of NH4+ and NO3− whereby higher values were reached at the end of spring–early summer, except at the easternmost coastal site of Begur. Weekly NH4+ concentrations decreased with time at all sites (except at La Senia) whilst NO3− concentrations increased at all sites during the same period. Rainfall SO42− concentrations decreased with time at all sites. The opposite trends in NO3− and SO42− concentrations determined a shift in the relative acid contribution of those anions during the 12–13-year period. To interpret the increasing trend, mean annual NO3− concentrations were regressed against NO$_{2}$ Spanish emissions and to some indicators of local anthropogenic activity. The increase at Sort and Palautordera showed good correlation with local anthropogenic indicators. Wet inorganic N deposition ranged between 4.2 and 6.7 kg ha$^{−1}$ year$^{−1}$. When including estimates of dry deposition, total annual deposition rose up to 10–20 kg ha$^{−1}$ year$^{−1}$, values that have been found to initiate adverse effects on Mediterranean-type forest ecosystems. |
| Starting Page | 123 |
| Ending Page | 138 |
| Page Count | 16 |
| File Format | |
| ISSN | 00496979 |
| Journal | Water, Air, and Soil Pollution |
| Volume Number | 207 |
| Issue Number | 1-4 |
| e-ISSN | 15732932 |
| Language | English |
| Publisher | Springer Netherlands |
| Publisher Date | 2009-06-16 |
| Publisher Place | Dordrecht |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Nitrate Ammonium Inter-annual trends Seasonal cycle Rural areas Mediterranean Climate Change Hydrogeology Soil Science & Conservation Waste Water Technology Water Pollution Control Water Management Aquatic Pollution Atmospheric Protection/Air Quality Control/Air Pollution Environment |
| Content Type | Text |
| Resource Type | Article |
| Subject | Ecological Modeling Environmental Chemistry Pollution Environmental Engineering Water Science and Technology |
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