NDLI: Determination of Rare Earth Elements by Solid Phase Extraction Using Chemically Modified Amberlite XAD-4 Resin and Inductively Coupled Plasma-Optical Emission Spectrometry

Content Provider	Springer Nature Link
Author	Karadaş, Cennet Kara, Derya
Copyright Year	2014
Abstract	A new solid phase extraction method was developed for the preconcentration and determination of the rare earth elements (REEs) Pr, Sm, Eu, Gd, Tb, Dy, Ho, Tm, Yb, and Lu at trace levels using a mini-column packed with 8-hydroxy-2-quinolinecarboxaldehyde functionalized Amberlite XAD-4 resin. The REE ions were adsorbed onto the resin and then eluted with 2 mL of 1.0 mol L$^{−1}$ HNO$_{3}$ solution and determined using inductively coupled plasma-optical emission spectrometry (ICP-OES). In order to achieve the best performance for the method, the effects of several parameters such as sample pH, sample and eluent flow rate, sample volume, and matrix ions on the method efficiency were investigated. Under the optimum conditions, detection limits between 0.010 and 0.420 μg L$^{−1}$ for a preconcentration factor of 12.5 were achieved. The sorption capacities for the resin were found to range between 49.6 μmol g$^{−1}$ (for Yb) and 112.4 μmol g$^{−1}$ (for Pr). In order to verify the accuracy of the developed method, a certified reference material (SPS-SW2 Batch 127 surface water) was analyzed, and the results obtained were in good agreement with the certified values. The method was also successfully applied to the determination of REEs in water samples with recoveries in the range of 88.4–100.5 % being obtained.
Starting Page	1
Ending Page	10
Page Count	10
File Format	PDF
ISSN	00496979
Journal	Water, Air, and Soil Pollution
Volume Number	225
Issue Number	11
e-ISSN	15732932
Language	English
Publisher	Springer International Publishing
Publisher Date	2014-10-17
Publisher Place	Cham
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Amberlite XAD-4 Inductively coupled plasma-optical emission spectrometry (ICP-OES) Preconcentration Rare earth elements (REEs) Solid phase extraction Waters 8-Hydroxy-2-quinolinecarboxaldehyde Environment Water Quality/Water Pollution Atmospheric Protection/Air Quality Control/Air Pollution Soil Science & Conservation Hydrogeology Climate Change/Climate Change Impacts
Content Type	Text
Resource Type	Article
Subject	Ecological Modeling Environmental Chemistry Pollution Environmental Engineering Water Science and Technology

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