NDLI: Tribological properties of self-assembled monolayers on Au, SiOx and Si surfaces

Content Provider	Springer Nature Link
Author	Kim, Hyun. I. Boiadjiev, V. Houston, J.E. Zhu, X. Y. Kiely, J.D.
Copyright Year	2001
Abstract	Using interfacial force microscopy (IFM), the tribological properties of self-assembled monolayers (SAM) on Si surfaces produced by a new chemical strategy are investigated and compared to those of “classical” SAM systems, which include alkanethiols on Au and alkylsilanes on SiO$_{x}$. The new SAM films are prepared by depositing n-alkyl chains with OH-terminations onto Cl-terminated Si substrates. The chemical nature of the actual lubricating molecules, n-dodecyl, is kept constant in all three thin film systems for direct comparison and similarities and differences in tribological properties are observed. The adhesion strength is virtually identical for all three systems; however, frictional properties differ due to differences in film packing. Differences in the chemical bonds that attach the lubricant molecules to the substrate are also discussed as they influence variations in film wear and durability. It is demonstrated that the new SAM films are capable of controlling the friction and adhesion of Si surfaces equally well as the classical SAMs and are potentially more reproducible and more durable.
Starting Page	97
Ending Page	101
Page Count	5
File Format	PDF
ISSN	10238883
Journal	Tribology Letters
Volume Number	10
Issue Number	1-2
e-ISSN	15732711
Language	English
Publisher	Kluwer Academic Publishers-Plenum Publishers
Publisher Date	2001-01-01
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Physical Chemistry Surfaces and Interfaces, Thin Films Mechanics
Content Type	Text
Resource Type	Article
Subject	Surfaces, Coatings and Films Mechanics of Materials Mechanical Engineering Surfaces and Interfaces

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