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| Content Provider | Springer Nature Link |
|---|---|
| Author | Zhou, Shengguo Wang, Liping Xue, Qunji |
| Copyright Year | 2012 |
| Abstract | Due to strongly tribological atmosphere sensitivity of carbon-based coatings, it is of extreme significance to investigate their friction and wear behaviors in different atmospheres. In this letter, duplex nc-TiC/a-C(Al) nanocomposite carbon-based coating coupled with high hardness, low internal stress and high adhesion strength was successfully fabricated using magnetron sputtering process. The friction and wear behaviors of as-fabricated coating were evaluated in dry N$_{2}$, humid N$_{2}$, air, dry O$_{2}$, and humid O$_{2}$ atmospheres, respectively. Results show that the as-fabricated coating possesses very high friction and wear due to the strong covalent bond interactions at the sliding interface caused by the free σ-bonds on the coating surface in dry N$_{2}$ atmosphere. Whereas the free σ-bonds can be efficiently terminated and passivated by water and/or oxygen molecules to weaken the strong covalent bond interactions to result in low friction and wear of coating in humid N$_{2}$, air, dry O$_{2}$, and humid O$_{2}$ atmospheres. The compact and homogeneous carbonaceous tribo-layer on the counterpart is mainly responsible for the lowest friction and wear of coating in humid N$_{2}$ atmosphere. Whereas the tribo-layer can be restrained to a certain extent by the tribo-chemical reaction, especially it results in a nearly negligible carbonaceous tribo-layer on the counterpart in dry O$_{2}$ atmosphere, which is mainly responsible for largely increased friction and wear of coating. |
| Starting Page | 435 |
| Ending Page | 446 |
| Page Count | 12 |
| File Format | |
| ISSN | 10238883 |
| Journal | Tribology Letters |
| Volume Number | 47 |
| Issue Number | 3 |
| e-ISSN | 15732711 |
| Language | English |
| Publisher | Springer US |
| Publisher Date | 2012-06-30 |
| Publisher Place | Boston |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | nc-TiC/a-C(Al) Nanocomposite Atmosphere Tribo-layer Surfaces and Interfaces, Thin Films Nanotechnology Tribology, Corrosion and Coatings Physical Chemistry Theoretical and Applied Mechanics |
| Content Type | Text |
| Resource Type | Article |
| Subject | Surfaces, Coatings and Films Mechanics of Materials Mechanical Engineering Surfaces and Interfaces |
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