NDLI: Mechanisms of hydrocarbon conversion reactions on heterogeneous catalysts: analogies with organometallic chemistry

Content Provider	Springer Nature Link
Author	Zaera, Francisco
Copyright Year	2005
Abstract	Catalysis is central to most industrial processes for chemical manufacturing. As catalytic processes have become more complex and more demanding, selectivity has become the central issue in their design. Selectivity is defined by the relative rates of competing reaction pathways available to crucial intermediates, and can be controlled by subtle changes in the nature of the catalyst, the reactants, and/or the reaction conditions. In order to be able to do this in a systematic manner, a good understanding of the catalytic reaction mechanisms is needed. Here a connection is drawn between the key elementary steps comprising hydrocarbon conversion reactions on surfaces and those known to occur on discrete organometallic complexes. This way, the hydrogenation, dehydrogenation, hydrogenolysis, chain growth, and isomerization reactions typical in heterogeneous catalysis are redefined in terms of hydride elimination, oxidative addition, reductive elimination, migratory insertion, and 1, 2-shift elementary steps, among others. It is suggested that the knowledge already available from organometallic chemistry can be used to further advance the understanding of the surface science involved in heterogeneous catalysis. Thanks to the commonality of the chemistry involved, a better synergy could also be established between homogeneous and heterogeneous catalytic development. These ideas are discussed in this article in a critical and personal way.
Starting Page	129
Ending Page	141
Page Count	13
File Format	PDF
ISSN	10225528
Journal	Topics in Catalysis
Volume Number	34
Issue Number	1-4
e-ISSN	15729028
Language	English
Publisher	Kluwer Academic Publishers-Plenum Publishers
Publisher Date	2005-01-01
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	heterogeneous catalysis surface science hydrocarbon conversion transition metals reaction mechanisms Physical Chemistry Industrial Chemistry/Chemical Engineering Catalysis Characterization and Evaluation Materials Pharmacy
Content Type	Text
Resource Type	Article
Subject	Chemistry Catalysis

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Reaction Mechanisms of Lean-Burn Hydrocarbon SCR over Zeolite Catalysts

Platinum group metals as heterogeneous enantioselective catalysts

Mechanisms of hydrocarbon conversion reactions on heterogeneous catalysts: analogies with organometallic chemistry

Surface Structure of Heterogeneous Catalysts: Cinchona and Tartaric Acid on Solid Surface

Surface organometallic chemistry on metals. Application to chemicals and fine chemicals

Surface Science Studies on the Zirconia-Based Model Catalysts

Characterization of Heterogeneous Catalysts by use of Test Reactions

Conversion of Triglycerides to Hydrocarbons Over Supported Metal Catalysts

The Transition State in Heterogeneous Catalysis

Mechanisms of hydrocarbon conversion reactions on heterogeneous catalysts: analogies with organometallic chemistry

Similar Documents

Reaction Mechanisms of Lean-Burn Hydrocarbon SCR over Zeolite Catalysts

Platinum group metals as heterogeneous enantioselective catalysts

Mechanisms of hydrocarbon conversion reactions on heterogeneous catalysts: analogies with organometallic chemistry

Surface Structure of Heterogeneous Catalysts: Cinchona and Tartaric Acid on Solid Surface

Surface organometallic chemistry on metals. Application to chemicals and fine chemicals

Surface Science Studies on the Zirconia-Based Model Catalysts

Characterization of Heterogeneous Catalysts by use of Test Reactions

Conversion of Triglycerides to Hydrocarbons Over Supported Metal Catalysts

The Transition State in Heterogeneous Catalysis

Mechanisms of hydrocarbon conversion reactions on heterogeneous catalysts: analogies with organometallic chemistry