NDLI: Exploring the Influence of the Nickel Oxide Species on the Kinetics of Hydrogen Electrode Reactions in Alkaline Media

Content Provider	Springer Nature Link
Author	Oshchepkov, Alexandr G. Bonnefont, Antoine Saveleva, Viktoriia A. Papaefthimiou, Vasiliki Zafeiratos, Spyridon Pronkin, Sergey N. Parmon, Valentin N. Saviva, Elena R.
Copyright Year	2016
Abstract	The influence of the oxidation of Ni electrodes on the kinetics of the hydrogen oxidation (HOR) and evolution reactions (HER) has been explored by combining an experimental cyclic voltammetry study, microkinetic modeling and X-ray photoelectron spectroscopic analysis. Almost 10 times enhancement of the activity of Ni in the HOR/HER has been observed after its oxidation under the contact with air at ambient conditions and assigned to the presence of NiO species on the surface of metallic Ni. The experimental cyclic voltammetry curves have been analyzed with the help of kinetic model in order to shed light on the mechanism of the HOR/HER for two types of Ni electrodes and its dependence on the presence of NiO on the surface of the electrode. The main features of the experimental current-potential curves can be reproduced with a kinetic model assuming that the free energy of the adsorbed hydrogen intermediate is increased and that the kinetics of the Volmer step is enhanced in the presence of nickel oxide species. The kinetic model provides evidence for the switching from the Heyrovsky–Volmer mechanism on metallic Ni to Tafel–Volmer mechanism on the activated electrode, where surface oxide species co-exist with metal Ni sites.
Starting Page	1319
Ending Page	1331
Page Count	13
File Format	PDF
ISSN	10225528
Journal	Topics in Catalysis
Volume Number	59
Issue Number	15-16
e-ISSN	15729028
Language	English
Publisher	Springer US
Publisher Date	2016-07-21
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Hydrogen oxidation and evolution reactions Alkaline solutions Nickel Nickel oxide X-ray photoelectron spectroscopy Kinetic modeling Catalysis Physical Chemistry Pharmacy Industrial Chemistry/Chemical Engineering Characterization and Evaluation of Materials
Content Type	Text
Resource Type	Article
Subject	Chemistry Catalysis

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

On the Effect of Cu on the Activity of Carbon Supported Ni Nanoparticles for Hydrogen Electrode Reactions in Alkaline Medium

Operando X-Ray Photoelectron Spectroscopy Studies of Aqueous Electrocatalytic Systems

The Partial Oxidation of Methane Over Pd/Al$_{2}$O$_{3}$ Catalyst Nanoparticles Studied In-Situ by Near Ambient-Pressure X-ray Photoelectron Spectroscopy

Ambient Pressure X-ray Photoelectron Spectroscopy for Probing Monometallic, Bimetallic and Oxide-Metal Catalysts Under Reactive Atmospheres and Catalytic Reaction Conditions

On the effect of temperature and surface oxidation on the kinetics of hydrogen electrode reactions on nickel in alkaline media

X-ray photoelectron spectroscopy as a tool for in-situ study of the mechanisms of heterogeneous catalytic reactions

Kinetics of Solid-State Reactions in Heterogeneous Catalysis from Time-Resolved X-Ray Absorption Spectroscopy

The chemisorption of nitric oxide and the oxidation of ammonia at Cu(110) surfaces: a X-ray photoelectron spectroscopy (XPS) and scanning tunnelling microscopy (STM) study

Modulation Excitation X-Ray Absorption Spectroscopy to Probe Surface Species on Heterogeneous Catalysts

Exploring the Influence of the Nickel Oxide Species on the Kinetics of Hydrogen Electrode Reactions in Alkaline Media

Similar Documents

On the Effect of Cu on the Activity of Carbon Supported Ni Nanoparticles for Hydrogen Electrode Reactions in Alkaline Medium

Operando X-Ray Photoelectron Spectroscopy Studies of Aqueous Electrocatalytic Systems

The Partial Oxidation of Methane Over Pd/Al$_{2}$O$_{3}$ Catalyst Nanoparticles Studied In-Situ by Near Ambient-Pressure X-ray Photoelectron Spectroscopy

Ambient Pressure X-ray Photoelectron Spectroscopy for Probing Monometallic, Bimetallic and Oxide-Metal Catalysts Under Reactive Atmospheres and Catalytic Reaction Conditions

On the effect of temperature and surface oxidation on the kinetics of hydrogen electrode reactions on nickel in alkaline media

X-ray photoelectron spectroscopy as a tool for in-situ study of the mechanisms of heterogeneous catalytic reactions

Kinetics of Solid-State Reactions in Heterogeneous Catalysis from Time-Resolved X-Ray Absorption Spectroscopy

The chemisorption of nitric oxide and the oxidation of ammonia at Cu(110) surfaces: a X-ray photoelectron spectroscopy (XPS) and scanning tunnelling microscopy (STM) study

Modulation Excitation X-Ray Absorption Spectroscopy to Probe Surface Species on Heterogeneous Catalysts

Exploring the Influence of the Nickel Oxide Species on the Kinetics of Hydrogen Electrode Reactions in Alkaline Media