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| Content Provider | Springer Nature Link |
|---|---|
| Author | ZHANG, DONGXIAO |
| Copyright Year | 1997 |
| Abstract | Groundwater contamination of organics has recently become a problem of growing concern over the resulting health and environmental problems. In general, the multiphase system of nonaqueous phase liquid (NAPL), water and air has to be studied in order to realistically describe the movement of such materials in the subsurface. Numerous models have been developed to study multiphase flow and/or multispecies transport in porous media. However, using models to study the influence of medium heterogeneity on such flow and transport is only a recent event. It has been demonstrated for single-phase flow and transport in saturated and unsaturated media that the study of medium heterogeneity is amenable to stochastic analysis. In this paper, we extend our Eulerian–Lagrangian stochastic theory for single-phase transport to the problem of multiphase–multispecies transport in randomly heterogeneous media under the conditions that the flow is steady-state and the phases are in local chemical equilibrium. We present theoretical expressions to describe the first two conditional moments of the random concentration of any species in any phase. Though they reveal some of the fundamental properties and help gaining insight into the nature of the problem, these expressions cannot be evaluated without either high resolution Monte Carlo simulation or approximation (closure). Therefore, we propose two sets of workable approximations, one being a weak approximation and the other being a linearized pseudo-Fickian approximation. The former yields a nonlinear integro-differential equation for the first conditional moment and the latter yields a linear differential equation. Then the second moments can be computed from explicit expressions from either the weak or pseudo-Fickian approximation. |
| Starting Page | 265 |
| Ending Page | 287 |
| Page Count | 23 |
| File Format | |
| ISSN | 01693913 |
| Journal | Transport in Porous Media |
| Volume Number | 27 |
| Issue Number | 3 |
| e-ISSN | 15731634 |
| Language | English |
| Publisher | Kluwer Academic Publishers |
| Publisher Date | 1997-01-01 |
| Publisher Place | Dordrecht |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Industrial Chemistry/Chemical Engineering Hydrogeology Geotechnical Engineering Mechanics, Fluids, Thermodynamics Civil Engineering |
| Content Type | Text |
| Resource Type | Article |
| Subject | Catalysis |
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