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| Content Provider | Springer Nature Link |
|---|---|
| Author | Samokhin, A. V. Alekseev, N. V. Korovkina, T. F. Troitskaya, E. V. Tsvetkov, Yu. V. |
| Copyright Year | 2007 |
| Abstract | The generation of atoms and radicals by the equilibrium thermal dissociation of oxygen and the same process involving water vapor are similar in terms of the reactive-species yield and energy consumption. The energy input into the generation of atoms and radicals is the smallest at 4500 K; about 70% of the energy is spent directly for the breaking of chemical bonds. From the calculations of the kinetics of oxygen atom recombination, it follows that cooling at a rate higher than 10$^{7}$ K/s makes it possible to achieve considerable deviations from the equilibrium atom concentration. The lifetime of atoms in cooling thermal plasma is estimated at 10$^{−5}$ s. It has been established experimentally that a thermal plasma jet plunging into the water bulk generates hydrogen peroxide. The totality of factors affecting the hydrogen peroxide accumulation rate can be represented in as a generalized parameter, specifically, the atomic oxygen feed rate. |
| Starting Page | 613 |
| Ending Page | 619 |
| Page Count | 7 |
| File Format | |
| ISSN | 00405795 |
| Journal | Theoretical Foundations of Chemical Engineering |
| Volume Number | 41 |
| Issue Number | 5 |
| e-ISSN | 16083431 |
| Language | English |
| Publisher | Nauka/Interperiodica |
| Publisher Date | 2007-01-01 |
| Publisher Place | Moscow |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Industrial Chemistry/Chemical Engineering |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Chemical Engineering |
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