NDLI: Synthesis, IR spectrum, thermal property and crystal structure of cyano-bridged heteronuclear polymeric complex, [Cd(teta)Ni(μ-CN)$_{2}$(CN)$_{2}$]

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Synthesis, IR spectrum, thermal property and crystal structure of cyano-bridged heteronuclear polymeric complex, [Cd(teta)Ni(μ-CN)$_{2}$(CN)$_{2}$] · 2H$_{2}$O

Content Provider	Springer Nature Link
Author	Kürkçüoğlu, Güneş Süheyla Hökelek, Tuncer Yeşilel, Okan Zafer Aksay, Sabiha
Copyright Year	2008
Abstract	The cyano-bridged heteronuclear polymeric complex, [Cd(teta)Ni(μ-CN)$_{2}$(CN)$_{2}$] · 2H$_{2}$O (1), (teta = triethylenetetraamine) was synthesized and characterized by FT-IR spectroscopy, thermal analysis and single crystal X-ray diffraction techniques. It crystallizes in the orthorhombic system, space group Pccn. The asymmetric unit also contains two uncoordinated water molecules. The coordination geometry around the Cd(II) centre is a highly distorted octahedral. In the crystal structure, intramolecular N–H···O and intermolecular N–H···O, O–H···O and O–H···N hydrogen bonds, beside the cyano-bridged chains made up of tetracyanonickelate ions coordinated to Cd(II) ions, where the Ni(II) ion is coordinated by four cyanoligands in a square-planar arrangement, link the molecules into polymeric networks parallel to (001) plane, where the hydrogen bonded water molecules occupy the cavities between the layers. The FT-IR spectrum was reported in the 4,000–400 cm$^{−1}$ region. Vibration assignments were given for all the observed bands and the spectral feature also supported the structure of the polymeric complex. The decomposition reaction takes place in the temperature range 20–1,000 °C in the static air atmosphere.
Starting Page	493
Ending Page	499
Page Count	7
File Format	PDF
ISSN	10400400
Journal	Structural Chemistry
Volume Number	19
Issue Number	3
e-ISSN	15729001
Language	English
Publisher	Springer US
Publisher Date	2008-03-27
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Cyano-bridged complex Tetracyanonickelate Infrared spectrum Crystal structure Triethylenetetraamine complex Theoretical and Computational Chemistry Physical Chemistry Computer Applications in Chemistry
Content Type	Text
Resource Type	Article
Subject	Physical and Theoretical Chemistry Condensed Matter Physics

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