NDLI: Synthesis, crystal, and molecular structure of coordination polymers constructed by self-assembly of NiN$_{4}$ cores with 2,2′-iminodibenzoate and nitroprusside ions

Please wait, while we are loading the content...

Synthesis, crystal, and molecular structure of coordination polymers constructed by self-assembly of NiN$_{4}$ cores with 2,2′-iminodibenzoate and nitroprusside ions

Cobalt-5-aminoisophthalate: [Co(AIPA)(OH$_{2}$)$_{2}$]$_{ n }$·nH$_{2}$O: a new one-dimensional rail-road polymer with occluded water molecules

Hydrogen-bonded supramolecular motifs in crystal structures of trimethoprim barbiturate monohydrate (I) and 2-amino-4,6-dimethylpyrimidinium barbiturate trihydrate (II)

Unsymmetrical 1-naphthyltellurium(IV) dihalides: the interplay of Te···Br, C–H···Br and C–H···π interactions in the crystal structure of (1-naphthyl)(4-methylphenyl)tellurium(IV) dibromide

Cis-Dioxomolybdenum(VI) complexes of sterically encumbered phenol-based tetradentate N$_{2}$O$_{2}$ ligands: Structural, spectroscopic, and electrochemical studies

Crystal structure and ionic conductivity of the series A$_{2}$Bi$_{24}$Mo$_{8}$X$_{2}$O$_{68}$ (A = Ca, Sr and Ba and X = Cr and W) in the Bi$_{2}$O$_{3}$−MoO$_{3}$ system

Tellurium-chlorine secondary interactions in palladium(II) complex of MeOC$_{6}$H$_{4}$TeCH$_{2}$CH$_{2}$NHCH(CH$_{3}$)C$_{6}$H$_{4}$-2-OH resulting in self-assembled bimolecular aggregates with short palladium-palladium distances

Synthesis, structure and electrochemical properties of some thiosemicarbazone complexes of iridium

Synthesis, characterization, and crystal structure of [Ni(dap(A)$_{2}$)]$_{2}$ (dap(AH)$_{2}$: 2,6-diacetylpyridine bis(anthraniloyl hydrazone))—a molecule possessing an infinite double helical chain in the solid state

Modification of supramolecular assemblies based on C$_{4}$H$_{7}$(CH$_{3}$)Te heterocycle and cooperative participation of intermolecular I···I, Te···I, Te···O secondary bonds; C(sp$^{3}$)–H···O and C(sp$^{2}$)–H···O hydrogen bonds

Synthesis and characterization of tribenzyltin(IV) and dibenzyltin(IV) complexes of 2-{[(2Z)-3-hydroxy-1-methyl- 2-butenylidene]amino}acetic acid: Crystal structure of tribenzyl{2-{[(2Z)-3-hydroxy-1-methyl-2-butenylidene] amino}acetato}tin(IV)

Synthesis, crystal and molecular structures of 1D and 2D supramers of copper(II) with N,N′-{bis(pyridin-2-yl) benzylidene}butane-1,4-diamine

X-ray structures of cobalt(III) complexes with bio-relevant pyrazolyl thiosemicarbazone: Indication of structural changes on the increasing bulkiness of the alkyl substituents on thiosemicarbazone moiety

Structural Chemistry : Volume 18, Issue 1, February 2007

Structural Chemistry : Volume 17

Structural Chemistry : Volume 16

Structural Chemistry : Volume 15

Structural Chemistry : Volume 14

Structural Chemistry : Volume 13

Structural Chemistry : Volume 12

Structural Chemistry : Volume 11

Structural Chemistry : Volume 10

Structural Chemistry : Volume 9

Structural Chemistry : Volume 8

Synthesis, crystal, and molecular structure of coordination polymers constructed by self-assembly of NiN$_{4}$ cores with 2,2′-iminodibenzoate and nitroprusside ions

Content Provider	Springer Nature Link
Author	Chakraborty, Jishnunil Shaikh, Nizamuddin Mayer Figge, Heike Sheldrick, William S. Vojtíšek, Pavel Banerjee, Pradyot
Copyright Year	2006
Abstract	Two coordination compounds of compositions [Ni(L$^{1}$)(idba)(H$_{2}$O)]·1.5 H$_{2}$O (1) and [Ni(L$^{2}$)Fe(CN)$_{5}$NO]·C$_{2}$H$_{5}$OH (2) where L$^{1}$ is N, N′-bis(3-aminopropyl)ethylenediamine, L$^{2}$ is 2,12-dimethyl-3,7,11,17-tetraazabicyclo[11.3.1]heptadeca-1(17),2,11,13,15-pentaene, and idba$^{2−}$ is 2,2′-iminodibenzoate have been synthesized and characterized by elemental analysis, IR spectroscopy, thermal analysis, and single-crystal X-ray diffraction. Complex 1 crystallizes in the monoclinic space group P2$_{1}$/n (No. 14) with a=9.810(2) Å, b=10.230(2) Å, c=25.350(5) Å, V=2543.6(9) Å$^{3}$, Z=4, and R=0.0727. The nickel atom is six-coordinated by four N atoms of amine and two O atoms of water and idba$^{2−}$. The molecular packing of the complex comprises of an infinite one-dimensional layered network in which the molecules in the crystal are held together by a system of hydrogen bonding. Complex 2, however, crystallizes in the space group C2/c (No. 15) of the monoclinic system with a=19.7990(4) Å, b=14.9440(3) Å, c=19.8800(3) Å, V=5115.90(17) Å$^{3}$, Z=4, and R=0.0540. The Ni ion in compound 2 has a slightly distorted octahedral arrangement of the N$_{4}$ donor atoms of primary ligand L$^{2}$ and two N-donor atoms of the secondary nitroprusside ligand. The structure of 2 displays an extended one-dimensional network formed by linear [—Ni—NC—Fe—CN—] units. A cyclic voltammetric study shows that compound 1 undergoes a quasireversible oxidation attributable to Ni$^{2+}$ → Ni$^{3+}$ in the range 300–420 mV vs SCE.
Starting Page	157
Ending Page	164
Page Count	8
File Format	PDF
ISSN	10400400
Journal	Structural Chemistry
Volume Number	18
Issue Number	2
e-ISSN	15729001
Language	English
Publisher	Kluwer Academic Publishers-Plenum Publishers
Publisher Date	2006-12-08
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Ni(II) coordination polymers Crystal structure Thermal analysis Cyclic voltammetry Theoretical and Computational Chemistry Physical Chemistry Computer Applications in Chemistry
Content Type	Text
Resource Type	Article
Subject	Physical and Theoretical Chemistry Condensed Matter Physics

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

pH-driven structure modulations in cobalt(II) coordination polymers constructed from 2,2'-bipyridine-5,5'-dicarboxylic acid

Synthesis, Crystal Structure, Physical Properties and Theoretical Calculations of a New One-Dimensional Ni(II) Coordination Polymer Constructed by 1,10-Phenanthroline Derivative Ligand and Sulfate

Synthesis, crystal structure, supramolecular assembly, and thermal stability of two new lanthanide coordination polymers based on α-naphthoxyacetate

Synthesis, Structure and Cyclic Voltammetry Studies of a 2D Sheet-like μ$_{3}$-Hydroxyl- and μ$_{2}$-, μ$_{4}$-Oxamidato-Bridged Copper(II) Complex

Synthesis, crystal structure, and properties of a three-dimensional coordination polymer [Cd(PMP)$_{2}$]$_{n}$

Synthesis and Crystal Structure of Nickel(II) Complex with 2,2′-Biimidazole and 4-Aminobenzoic Acid

Synthesis and Crystal Structures of pH-Dependent Ni(II) Coordination Polymers with 3-Pyrid-3-ylbenzoic Acid

Crystal structure and fluorescence/phosphorescence of two novel Cd(II) coordination polymers

Synthesis, crystal structure, and electrochemical properties of Ni(II) and Cu(II) complexes with two unsymmetrical N$_{2}$O$_{2}$ Schiff base ligands

Synthesis, crystal, and molecular structure of coordination polymers constructed by self-assembly of NiN$_{4}$ cores with 2,2′-iminodibenzoate and nitroprusside ions

Similar Documents

pH-driven structure modulations in cobalt(II) coordination polymers constructed from 2,2'-bipyridine-5,5'-dicarboxylic acid

Synthesis, Crystal Structure, Physical Properties and Theoretical Calculations of a New One-Dimensional Ni(II) Coordination Polymer Constructed by 1,10-Phenanthroline Derivative Ligand and Sulfate

Synthesis, crystal structure, supramolecular assembly, and thermal stability of two new lanthanide coordination polymers based on α-naphthoxyacetate

Synthesis, Structure and Cyclic Voltammetry Studies of a 2D Sheet-like μ$_{3}$-Hydroxyl- and μ$_{2}$-, μ$_{4}$-Oxamidato-Bridged Copper(II) Complex

Synthesis, crystal structure, and properties of a three-dimensional coordination polymer [Cd(PMP)$_{2}$]$_{n}$

Synthesis and Crystal Structure of Nickel(II) Complex with 2,2′-Biimidazole and 4-Aminobenzoic Acid

Synthesis and Crystal Structures of pH-Dependent Ni(II) Coordination Polymers with 3-Pyrid-3-ylbenzoic Acid

Crystal structure and fluorescence/phosphorescence of two novel Cd(II) coordination polymers

Synthesis, crystal structure, and electrochemical properties of Ni(II) and Cu(II) complexes with two unsymmetrical N$_{2}$O$_{2}$ Schiff base ligands

Synthesis, crystal, and molecular structure of coordination polymers constructed by self-assembly of NiN$_{4}$ cores with 2,2′-iminodibenzoate and nitroprusside ions