NDLI: Synthesis, structure, and photophysical property of series of Ln(III) coordination polymers with different carboxylato ligands (Ln = Sm, Eu)

Content Provider	Springer Nature Link
Author	Jin, Jing Wang, Xiuyan Li, Yanying Chi, Yuxian Niu, Shuyun
Copyright Year	2012
Abstract	Four Ln(III) coordination polymers, {[Ln$_{2}$(1,3-bdc)$_{3}$(H$_{2}$O)$_{4}$]·DMF·H$_{2}$O}$_{ n }$ (Ln = Sm 1, Eu 2) and [Ln$_{2}$(mal)$_{3}$(H$_{2}$O)$_{6}$]$_{ n }$ (Ln = Sm 3, Eu 4) (1,3-H$_{2}$bdc = isophthalate acid, H$_{2}$mal = malonate acid), were hydrothermally synthesized and characterized by single-crystal X-ray diffraction, elemental analysis, IR spectra, UV–Vis–NIR absorption spectra, and fluorescence spectra. The structural analyses reveal that polymer 1 is a 3D coordination polymer. Its asymmetry unit contains two crystallographically independent Sm(III) ions, both are eight-coordinated. The 1,3-bdc$^{2−}$ anions show three different coordination modes. The structure of polymer 2 is isomorphous with that of 1. Polymer 3 is also a 3D coordination polymer, its asymmetry unit contains one Sm(III) ion, which is nine-coordinate. The mal$^{2−}$ anions have two different coordination modes. The structure of polymer 4 is isomorphous with that of 3. The luminescent study shows that polymers 1, 2, and 4 exhibit characteristic emission bands in the visible region, corresponding to the transitions of the Ln(III) ions. By comparison and analysis of luminescence, it is found that the incidence of the same ligand on the corresponding spectra of different Ln(III) ions is different, and the influence of different ligands on luminescence of the same Ln(III) ion is also very different.
Starting Page	1523
Ending Page	1531
Page Count	9
File Format	PDF
ISSN	10400400
Journal	Structural Chemistry
Volume Number	23
Issue Number	5
e-ISSN	15729001
Language	English
Publisher	Springer US
Publisher Date	2012-02-15
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Ln(III) coordination polymer Synthesis Crystal structure Photophysical property Physical Chemistry Computer Applications in Chemistry Theoretical and Computational Chemistry
Content Type	Text
Resource Type	Article
Subject	Physical and Theoretical Chemistry Condensed Matter Physics

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Syntheses, Crystal Structures and Photophysical Properties of a Series of Ln$^{III}$ (Ln = Sm, Tb, Pr) Coordination Polymers

Crystal structure and fluorescence/phosphorescence of two novel Cd(II) coordination polymers

Two new lead(II) coordination polymer and discrete complex containing bipyridine ligands with different positioned methyl substituents: synthesis, characterization, crystal structure determination, and luminescent properties

Synthesis, Crystal Structure and Magnetic Property of a One-Dimensional Samarium(III) Coordination Polymer

Synthesis, Crystal Structures and Magnetic Properties of Two Three-Dimensional Cerium(III) and Erbium(III) Coordination Polymers

Coordination polymers with adamantanediacetate bridges: syntheses, structures, and magnetic properties

Synthesis, crystal structure, supramolecular assembly, and thermal stability of two new lanthanide coordination polymers based on α-naphthoxyacetate

Ligand-directed copper(І) azide coordination polymers bridged by N-donor ligands with different lengths: azide exhibits a rare μ−1, 1, 3, 3 bridging mode

Synthesis and molecular structure of potassium 3,5-dinitrophloroglucinolsulfonate monohydrate

Synthesis, structure, and photophysical property of series of Ln(III) coordination polymers with different carboxylato ligands (Ln = Sm, Eu)

Similar Documents

Syntheses, Crystal Structures and Photophysical Properties of a Series of Ln$^{III}$ (Ln = Sm, Tb, Pr) Coordination Polymers

Crystal structure and fluorescence/phosphorescence of two novel Cd(II) coordination polymers

Two new lead(II) coordination polymer and discrete complex containing bipyridine ligands with different positioned methyl substituents: synthesis, characterization, crystal structure determination, and luminescent properties

Synthesis, Crystal Structure and Magnetic Property of a One-Dimensional Samarium(III) Coordination Polymer

Synthesis, Crystal Structures and Magnetic Properties of Two Three-Dimensional Cerium(III) and Erbium(III) Coordination Polymers

Coordination polymers with adamantanediacetate bridges: syntheses, structures, and magnetic properties

Synthesis, crystal structure, supramolecular assembly, and thermal stability of two new lanthanide coordination polymers based on α-naphthoxyacetate

Ligand-directed copper(І) azide coordination polymers bridged by N-donor ligands with different lengths: azide exhibits a rare μ−1, 1, 3, 3 bridging mode

Synthesis and molecular structure of potassium 3,5-dinitrophloroglucinolsulfonate monohydrate

Synthesis, structure, and photophysical property of series of Ln(III) coordination polymers with different carboxylato ligands (Ln = Sm, Eu)