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Syntheses, structures, and magnetic properties of new rare earth coordination polymers constructed by 1,3,5-benzenetriacetic acid

Content Provider	Springer Nature Link
Author	Zhang, Zheng Hua Liu, Guang Xiang Okamura, Taka aki Sun, Wei Yin Ueyama, rikazu
Copyright Year	2006
Abstract	Three new coordination polymers with formula [Gd(bta)(H$_{2}$O)·1.39H$_{2}$O]$_{ n }$ (1), [Dy(bta)(H$_{2}$O)·1.35H$_{2}$O]$_{ n }$ (2) and [Y(bta)(H$_{2}$O)$_{2}$·0.5H$_{2}$O]$_{ n }$ (3) were synthesized by using corresponding rare earth nitrates and 1,3,5-benzenetriacetic acid (H$_{3}$bta) under hydrothermal/solvothermal reaction conditions, and characterized by single-crystal X-ray diffraction. In these complexes, the carboxylate groups of bta$^{3−}$ adopt different coordination modes, namely one carboxylate group adopts μ$_{2}$-η$^{1}$:η$^{1}$-bridging and each of the other two carboxylate groups adopts μ$_{2}$-η$^{2}$:η$^{1}$-bridging coordination modes in 1 and 2, and one carboxylate group adopts a μ$_{2}$-η$^{2}$:η$^{1}$-bridging coordination mode and each of the other two carboxylate groups adopts a μ$_{2}$-η$^{1}$:η$^{1}$-bridging mode for the major component and one carboxylate group adopts a μ$_{2}$-η$^{2}$:η$^{1}$-bridging coordination mode, one has a μ$_{2}$-η$^{1}$:η$^{1}$-bridging mode and the third has a monodentate mode for the minor component in 3. The magnetic properties of the complexes 1 and 2 were investigated in the temperature range of 1.8–300 K.
Starting Page	3
Ending Page	11
Page Count	9
File Format	PDF
ISSN	10400400
Journal	Structural Chemistry
Volume Number	17
Issue Number	1
e-ISSN	15729001
Language	English
Publisher	Springer US
Publisher Date	2006-04-20
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Rare earth Coordination polymers Crystal structures Magnetic properties Theoretical and Computational Chemistry Physical Chemistry Computer Applications in Chemistry
Content Type	Text
Resource Type	Article
Subject	Physical and Theoretical Chemistry Condensed Matter Physics

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