NDLI: Fullerene black: Structure, properties and possible applications

Content Provider	Springer Nature Link
Author	Kushch, S. D. Kuyunko, N. S.
Copyright Year	2011
Abstract	This review concerns the fullerene black, a poorly known nano-sized carbon material, the insoluble residue after extraction of fullerenes from fullerene soot obtained by arc vaporization of carbon material (usually graphite) in a helium atmosphere. This by-product of the production of fullerenes, whose yield reaches 80 wt %, is a finely dispersed material with a particle size of 40–50 nm. It includes amorphous carbon, graphitized particles, and graphite. Test reactions showed the presence in the structure of fullerene black of curved surfaces, and, like fullerenes, of alternating nonconjugated ordinary and double bonds. In addition to the double bonds, its structure includes dangling bonds in the concentration not higher than one per 1200 carbon atoms. Fullerene black absorbs oxygen from the atmosphere and water, and enters into the reactions of nucleophilic addition. The fullerene black cannot be graphitized, and its application is extremely important. The fullerene black was shown to activate hydrogen and thus to undergo a hydrogenolysis in the absence of a catalyst and to catalyze the dehydrogenation and dehydrocyclization of alkanes. This carbon nanomaterial can be used as a sorbent and a catalyst carrier, a tribotechnical additive; it can interact with carbide-forming metals and harden their surface.
Starting Page	345
Ending Page	353
Page Count	9
File Format	PDF
ISSN	10703632
Journal	Russian Journal of General Chemistry
Volume Number	81
Issue Number	2
e-ISSN	16083350
Language	English
Publisher	SP MAIK Nauka/Interperiodica
Publisher Date	2011-03-25
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Chemistry/Food Science
Content Type	Text
Resource Type	Article
Subject	Chemistry

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Fullerene black: Structure, properties and possible applications

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