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| Content Provider | Springer Nature Link |
|---|---|
| Author | Stepav, R. S. Kruglyakova, L. A. Astakhov, A. M. |
| Copyright Year | 2007 |
| Abstract | Kinetics of liquid-phase thermal decomposition of a series of triazoles and tetrazoles containing a gem-trinitromethyl group were studied by manometry and photoelectrocolorimetry, and the mechanism of the thermal decomposition was established. The activation parameters of the rate-limiting stage of the process were evaluated. It was shown that the thermal stability of the gem-trinitromethyl group varies over a broad range, depending on the steric effect of the azole. The rate constant and activation energy correlate with the steric effect of the azole. The thermal decomposition of β-trinitroethylaminotetrazoles proceeds heterolytically with initial dissociation of the C-C bond to give a carbocation and the nitroform anion. |
| Starting Page | 1933 |
| Ending Page | 1938 |
| Page Count | 6 |
| File Format | |
| ISSN | 10703632 |
| Journal | Russian Journal of General Chemistry |
| Volume Number | 77 |
| Issue Number | 11 |
| e-ISSN | 16083350 |
| Language | English |
| Publisher | Nauka/Interperiodica |
| Publisher Date | 2007-01-01 |
| Publisher Place | Moscow |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Chemistry/Food Science |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry |
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