NDLI: Electrodeposition of nickel-based nanocomposite coatings from cerium(III)-ion-containing methanesulfonate electrolytes

Content Provider	Springer Nature Link
Author	Danilov, F. I. Sknar, Yu. E. Tkach, I. G. Sknar, I. V.
Copyright Year	2015
Abstract	It is found experimentally that electrodeposition of coatings from nickel(II)- and cerium(III)-ion-containing methanesulfonate electrolytes results in formation of nickel-matrix-deposits with ceriumoxide-compound inclusions. Increase in the cerium(III) concentration in the electrolyte, as well, as in the electrodeposition current density and electrolysis temperature, leads to increase in the cerium content in the deposits. The experimental data are in good agreement with the nickel-cerium coating formation scheme that implies the cerium oxide compounds to arise directly at the cathode surface due to pH increase in the near-electrode space as a result of hydrogen-evolution side reaction. The effect of nanosized cerium-containing oxide particles on the composite microhardness can be explained theoretically in terms of the dispersive hardening and the hardening caused by grain diminishment.
Starting Page	294
Ending Page	298
Page Count	5
File Format	PDF
ISSN	10231935
Journal	Russian Journal of Electrochemistry
Volume Number	51
Issue Number	4
e-ISSN	16083342
Language	English
Publisher	Pleiades Publishing
Publisher Date	2015-04-16
Publisher Place	Moscow
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	nanocomposite coatings nickel matrix methanesulfonate electrolyte cerium(III)-ions structure Electrochemistry Physical Chemistry
Content Type	Text
Resource Type	Article
Subject	Electrochemistry

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