NDLI: Double Electric Layer on Liquid Sn-Ga Alloy in Acetonitrile Solutions of Electrolytes

Content Provider	Springer Nature Link
Author	Emets, V. V. Damaskin, B. B.
Copyright Year	2005
Abstract	The structure of the double electric layer (DEL) on a liquid dropping Sn-Ga electrode containing 8 at. % of Sn is studied in acetonitrile (AN) solutions of electrolytes. It is shown that the transition from aqueous to AN solutions of electrolytes makes it possible to expand the region of investigation of parameters of DEL on an Sn-Ga electrode from negative charges to a zero charge and to small positive charges. As follows from the obtained data, throughout the entire interval of charges studied, an excess, as compared with an Hg electrode, chemisorption interaction (Sn-Ga)-AN is absent. It is established that the distance of the closest approach of AN dipoles to an ionic core increases upon going from Hg to Sn-Ga to Ga. The Ga, Bi-Ga, and Sn-Ga electrodes, which possess close values of the “electrochemical work function,” are used as an example to show that the metal-solvent chemisorption interaction increases with decreasing distance of the closest approach of its dipoles to the ionic core of the metal. The effect of this factor becomes stronger as the donor number of the solvent increases.
Starting Page	1038
Ending Page	1045
Page Count	8
File Format	PDF
ISSN	10231935
Journal	Russian Journal of Electrochemistry
Volume Number	41
Issue Number	10
e-ISSN	16083342
Language	English
Publisher	Nauka/Interperiodica
Publisher Date	2005-01-01
Publisher Place	Moscow
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	double electric layer alloy Sn-Ga acetonitrile metal-solvent interaction Physical Chemistry Electrochemistry
Content Type	Text
Resource Type	Article
Subject	Electrochemistry

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