NDLI: The study of copper dissolution in aqueous and nonaqueous systems DMSO-HX$_{solv}$ (solv = H$_{2}$O, X = Br, Cl; solv = MeCN, PhNO$

Please wait, while we are loading the content...

The study of copper dissolution in aqueous and nonaqueous systems DMSO-HX$_{solv}$ (solv = H$_{2}$O, X = Br, Cl; solv = MeCN, PhNO$_{2}$; X = Cl) by resistometric method

ESR study of paramagnetic derivatives of sterically hindered di-o-quinone with the tetrathiafulvalene bridge

Regioselectivity of the addition of $^{•}$CCl$_{3}$ and $^{•}$Bu$^{t}$ radicals to (η$^{2}$-C$_{70}$)[Os(CO)(PPh$_{3}$)$_{2}$(CNBu$^{t}$)]$_{n}$ (n = 1, 2): an ESR study

Effect of Pt nanoparticle size on the specific catalytic activity of Pt/SiO$_{2}$ and Pt/TiO$_{2}$ in the total oxidation of methane and n-butane

Synthesis of a hybrid material from CdS nanoparticles and carbon nanotubes

Poly(naphthalenehydrocarbyne): synthesis, characterization, and application to preparation of thin diamond films

New molecular magnetic metals: κ-(BDH-TTP)$_{4}$CuCl$_{4}$·(H$_{2}$O)$_{n}$ and κ-(BDH-TTP)$_{2}$[CuCl$_{4}$]$_{0.67}$·(H$_{2}$O)$_{0.33}$ (BDH-TTP is 2,5-bis(1,3-dithiolan-2-ylidene)-1,3,4,6-tetrathiapentalene)

Solid-phase mechanochemical synthesis of zirconium tetracarboxylates

P,C,P-Pincer complexes of ruthenium based on ruthenocene and pentamethylruthenocene

Supramolecular systems based on 1-alkyl-4-aza-1-azoniabicyclo[2.2.2]octane bromides

Asymmetric azomethine ligands based on 2-[(2-aminophenyl)aminomethylidene]-3-oxo-3-polyfluoroalkylpropionates and aldehydes

Asymmetric hydrogenation of methyl (Z)-2-acetamido-3-(3,4-dimethoxyphenyl)acrylate catalyzed by Rh complexes with available amidophosphite ligands

Hydrosilylation of non-1-ene with phenylsilane in the presence of yttrium and lutetium bisguanidinate hydride complexes

Reaction of unsaturated compounds with ethyl benzenesulfenate and trimethylsilyl isothiocyanate

Reaction of echinochrome trimethyl ether with aqueous ammonia

Nitropyrazoles : 19. Selective nucleophilic substitution of a nitro group in 3,4-dinitropyrazoles

Reactions of fluoroalkyl-containing lithium 1,3-diketonates with diaminoarenes and 2-aminobenzenethiol

Reaction of 5-methyl-1,3,4-thiadiazoline-2-thione with molecular iodine

Synthesis of 4-alkyl-3,4-dihydronaphtho[2,3-f]quinoxaline-2,7,12-(1H)-triones and 3-alkyl-5-arylamino-2-chloromethyl-3H-anthra[1,2-d]imidazole-6,11-diones based on reactions of 1-amino-9,10-anthraquinones with chloroacetyl chloride

Synthesis of symmetrical di(pyrimidin-2-yl)-1,2,4-triazoles and di(pyrimidin-2-yl)-1,2,4,5-tetrazines

Mechanism of the migration of the substituent in 1,2,3,7a-tetrahydroimidazo[1,2-b]isoxazole derivatives

Cellulose destruction by electron-beam-induced heating

Potassium as a promoter in the Co-based Fischer-Tropsch catalysis

Asymmetric hydrogenation with the use of chiral carborane amidophosphite derivatives in supercritical carbon dioxide and CH$_{2}$Cl$_{2}$

Efficient catalysis of the Suzuki-Miyaura reaction under mild conditions with cyclopalladated N,N-dimethylaminomethylferrocene

Chemiluminescence upon the oxidation of fullerene fluorides C$_{60}$F$_{x}$ (x = 18, 36, 48) with ozone in solution

Information ( Russian Chemical Bulletin , Volume 59 , Issue 9 )

Russian Chemical Bulletin : Volume 59, Issue 8, August 2010

Russian Chemical Bulletin : Volume 59, Issue 7, July 2010

Russian Chemical Bulletin : Volume 59, Issue 6, June 2010

Russian Chemical Bulletin : Volume 59, Issue 5, May 2010

Russian Chemical Bulletin : Volume 59, Issue 4, April 2010

Russian Chemical Bulletin : Volume 59, Issue 3, March 2010

Russian Chemical Bulletin : Volume 59, Issue 2, February 2010

Russian Chemical Bulletin : Volume 59, Issue 1, January 2010

Russian Chemical Bulletin : Volume 58

Russian Chemical Bulletin : Volume 57

Russian Chemical Bulletin : Volume 56

Russian Chemical Bulletin : Volume 55

Russian Chemical Bulletin : Volume 54

Russian Chemical Bulletin : Volume 53

Russian Chemical Bulletin : Volume 52

Russian Chemical Bulletin : Volume 51

Russian Chemical Bulletin : Volume 50

Russian Chemical Bulletin : Volume 49

Russian Chemical Bulletin : Volume 48

Russian Chemical Bulletin : Volume 47

Russian Chemical Bulletin : Volume 46

The study of copper dissolution in aqueous and nonaqueous systems DMSO-HX$_{solv}$ (solv = H$_{2}$O, X = Br, Cl; solv = MeCN, PhNO$_{2}$; X = Cl) by resistometric method

Content Provider	Springer Nature Link
Author	Shirshova, L. V. Lavrent’ev, I. P. Kokoreva, S. G.
Copyright Year	2010
Abstract	Copper dissolution in the aqueous systems DMSO-HX$_{solv}$ (solv = H$_{2}$O; X = Cl, Br) under the inert atmosphere and under aerobic conditions at different acid concentrations was studied by the resistometric method by measuring the resistance of a metal sample in the course of the reaction. The overall activity of the system decreases with a decrease in the concentration of the starting hydrohalic acid. The rate of copper dissolution in the extremum points also decreases. The process of the metallic copper dissolution in nonaqueous systems, such as DMSO-HCl$_{solv}$ (solv = MeCN, PhNO$_{2}$), was studied. In the latter systems, as opposed to aqueous systems, only one maximum in the plot of the copper dissolution rate versus the component ratio is observed. The change in the nature of the solvent in the donor-acceptor electron transport system DMSO-HCl$_{solv}$ (solv = H$_{2}$O, MeCN, PhNO$_{2}$) results in the change in the position of the maximum of the copper dissolution rate, as well as in the change in its value. The rate of copper dissolution in the above mentioned systems varies in the following series: H$_{2}$O < MeCN < PhNO$_{2}$.
Starting Page	1692
Ending Page	1697
Page Count	6
File Format	PDF
ISSN	10665285
Journal	Russian Chemical Bulletin
Volume Number	59
Issue Number	9
e-ISSN	15739171
Language	English
Publisher	Springer US
Publisher Date	2011-01-26
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	dimethyl sulfoxide hydrohalic acids water dipolar aprotic solvents copper oxidative dissolution complexation adsorption Inorganic Chemistry Organic Chemistry Chemistry/Food Science
Content Type	Text
Resource Type	Article
Subject	Chemistry

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Dissolution of copper and gold in the donor-acceptor systems DMSO-NH$_{4}$X$_{aq}$ (X = Cl, Br, and I) and NH$_{4}$I$_{aq}$-O$_{2}$

Osmium dimethyl sulfoxide complexes: Synthesis and properties of [H(dmso)$_{2}$][Os$^{III}$(dmso)$_{2}$Br$_{4}$]

Ionic entropies of transfer from water to nonaqueous solvents

Switchable solvents

Gibbs energies of transferring triglycine from water into H$_{2}$O-DMSO solvent

Synthesis and structure of [H(DMSO)$_{2}$]$_{2}$[OsX$_{6}$] (X = Cl, Br)

Solvation and complexation of copper (II) and chloride ions in 2,2,2-trifluoroethanol–dimethyl sulphoxide mixtures

Thermodynamic and transport studies of some multi_charged electrolytes in binary mixtures of aqueous dipolar aprotic solvents

Dissolution of noble metals and copper in the DMSO-HBr$_{aq}$ system

The study of copper dissolution in aqueous and nonaqueous systems DMSO-HX$_{solv}$ (solv = H$_{2}$O, X = Br, Cl; solv = MeCN, PhNO$_{2}$; X = Cl) by resistometric method

Similar Documents

Dissolution of copper and gold in the donor-acceptor systems DMSO-NH$_{4}$X$_{aq}$ (X = Cl, Br, and I) and NH$_{4}$I$_{aq}$-O$_{2}$

Osmium dimethyl sulfoxide complexes: Synthesis and properties of [H(dmso)$_{2}$][Os$^{III}$(dmso)$_{2}$Br$_{4}$]

Ionic entropies of transfer from water to nonaqueous solvents

Switchable solvents

Gibbs energies of transferring triglycine from water into H$_{2}$O-DMSO solvent

Synthesis and structure of [H(DMSO)$_{2}$]$_{2}$[OsX$_{6}$] (X = Cl, Br)

Solvation and complexation of copper (II) and chloride ions in 2,2,2-trifluoroethanol–dimethyl sulphoxide mixtures

Thermodynamic and transport studies of some multi_charged electrolytes in binary mixtures of aqueous dipolar aprotic solvents

Dissolution of noble metals and copper in the DMSO-HBr$_{aq}$ system

The study of copper dissolution in aqueous and nonaqueous systems DMSO-HX$_{solv}$ (solv = H$_{2}$O, X = Br, Cl; solv = MeCN, PhNO$_{2}$; X = Cl) by resistometric method