NDLI: First radical cаtion salt of bis(ethylenedithio)tetrathiafulvalene with organic anion [С(NCN)$_{2}$NH$_{2}$]$^{–}$: synthesis, structure, and conducting properties

Content Provider	Springer Nature Link
Author	Kushch, N. D. Spitsina, N. G. Kolesnikova, A. M. Simov, S. V.
Copyright Year	2016
Abstract	The electrochemical oxidation of bis(ethylenedithio)tetrathiafulvalene (ET) in the presence of simple dicyanamide salts of rare-earth metals with the general formula M[N(CN)$_{2}$]$_{3}$ (M = Gd$^{3+}$, Dy$^{3+}$, and Ho$^{3+}$) as electrolytes was studied for the first time. A novel radicalcаtion salt α-ЕТ$_{2}$[С(NCN)$_{2}$NH$_{2}$] with the unexpected (2,1-dicyano)guanidine anion was synthesized. The crystal structure of the salt and its conducting properties were studied. The structure of the salt is layered with alternating conducting radical-cation and insulating anionic layers. The cationic layers of the α-type are formed by two crystallographically independent radical-cations of ET of various charges. The anionic layers are formed of [С(NCN)$_{2}$NH$_{2}$]$^{–}$ anions linked by hydrogen contacts into chains. The crystals of ЕТ$_{2}$[С(NCN)$_{2}$NH$_{2}$] demonstrate a semiconducting character of conductivity in a temperature range of 300—100 K.
Starting Page	2034
Ending Page	2039
Page Count	6
File Format	PDF
ISSN	10665285
Journal	Russian Chemical Bulletin
Volume Number	65
Issue Number	8
e-ISSN	15739171
Language	English
Publisher	Springer US
Publisher Date	2017-03-28
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	radical-cаtion salt bis(ethylenedithio)tetrathiafulvalene dicyanamide salts of rare-earth metals electrocrystallization structure conductivity Chemistry/Food Science Organic Chemistry Inorganic Chemistry
Content Type	Text
Resource Type	Article
Subject	Chemistry

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