NDLI: Quaternary ammonium derivatives of natural terpenoids. Synthesis and properties

Content Provider	Springer Nature Link
Author	Kataev, V. E. Strobykina, I. Yu. Zakharova, L. Ya.
Copyright Year	2014
Abstract	In this review, we summarized and analyzed the literature data (from 1963 to March, 2014) on the synthesis and properties of quaternary ammonium derivatives of citronellal, menthol, camphor, lambertian acid, dehydroabietic acid, levopimaric acid, isosteviol, steviol, betulinic acid, dihydrobetulinic acid, platanic acid, oleanolic acid, ursolic acid, and polyprenols. Functionalization of terpenoids with ammnoium groups offers them new properties, such as cholinotropic, antiviral, and antimicrobial activities, or transforms them into chiral ionic liquids having a practical potential for application as chiral phasetransfer catalysts. The synthesis of ammonium derivatives of terpenoids possessing properties of cationic lipids or dimeric bis-quaternary ammonium surfactants was proved to have a promising outlook. A specific attention was paid to the method developed for transformation of any hydrophobic terpenoid or steroid into an amphiphilic water-soluble compound self-organized in the aqueous medium into vesicles (liposomes) forming cell-penetrating complexes with DNA.
Starting Page	1884
Ending Page	1900
Page Count	17
File Format	PDF
ISSN	10665285
Journal	Russian Chemical Bulletin
Volume Number	63
Issue Number	9
e-ISSN	15739171
Language	English
Publisher	Springer US
Publisher Date	2015-05-26
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	quaternary ammonium compounds terpenoids camphor resin acids isosteviol steviol polylprenols antimicrobial activity DNA transport Chemistry/Food Science Organic Chemistry Inorganic Chemistry
Content Type	Text
Resource Type	Book Review
Subject	Chemistry

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