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  1. Russian Journal of Applied Chemistry
  2. Russian Journal of Applied Chemistry : Volume 86
  3. Russian Journal of Applied Chemistry : Volume 86, Issue 2, February 2013
  4. Cross-linking of oligoalumosiloxanes
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Russian Journal of Applied Chemistry : Volume 90
Russian Journal of Applied Chemistry : Volume 89
Russian Journal of Applied Chemistry : Volume 88
Russian Journal of Applied Chemistry : Volume 87
Russian Journal of Applied Chemistry : Volume 86
Russian Journal of Applied Chemistry : Volume 86, Issue 12, December 2013
Russian Journal of Applied Chemistry : Volume 86, Issue 11, November 2013
Russian Journal of Applied Chemistry : Volume 86, Issue 10, October 2013
Russian Journal of Applied Chemistry : Volume 86, Issue 9, September 2013
Russian Journal of Applied Chemistry : Volume 86, Issue 8, August 2013
Russian Journal of Applied Chemistry : Volume 86, Issue 7, July 2013
Russian Journal of Applied Chemistry : Volume 86, Issue 6, June 2013
Russian Journal of Applied Chemistry : Volume 86, Issue 5, May 2013
Russian Journal of Applied Chemistry : Volume 86, Issue 4, April 2013
Russian Journal of Applied Chemistry : Volume 86, Issue 3, March 2013
Russian Journal of Applied Chemistry : Volume 86, Issue 2, February 2013
Continuous recovery of uranium oxides by electrolysis of M$_{2}$MoO$_{4}$-M$_{2}$Mo$_{2}$O$_{7}$-UO$_{2}$MoO$_{4}$ melts (M = Li, Na, K, Cs)
Cross-linking of oligoalumosiloxanes
Influence of maturation conditions of hydroxyapatite gel on the composition of xerogel
Synthesis of double oxides TiO$_{2}$-SiO$_{2}$ with low titanium content by hydrolysis of tetrabutoxytitanium-tetraethoxysilane mixture in an atmosphere of water vapor and ammonia
Development of procedures for preparing sorbents with improved structural characteristics from anthracite mining waste
Preparation of polybenzimidazoles by oxidative dehydrocyclization of polyamidines
New products of a new method for pyrolysis of pyridine
Synthesis of ɛ-caprolactone with stable hydrogen peroxide adducts
Electrolytic deposition of a cobalt-lead alloy with magnetic properties
Electrodialytic separation of cobalt(II) and nickel(II) using liquid membranes based on tri-n-octylamine and trialkylbenzylammonium chloride
Thallium-selective sensor with a membrane based on Tl$_{4}$HgI$_{6}$ ionic conductor
Dependence of the stability of a soap stock emulsion on the combined effect of sodium chloride and nonionogenic surfactant additives
Flotation activity of polymer anionic surfactants in the case of flotation desliming of sylvinite ore
Surface modification of iron particles with a polyfluorinated disulfude: Effect of solvent and temperature
Deviations from the temperature-defect law
Kinetics of mass transfer in the course of liquid extraction in stirred vessels
Influence of the chemical structure of fluorinated radicals in acrylated derivatives of Boltorn™ H20 hyperbranched polyesterpolyol on the surface energy of coatings prepared from UV-curable powder formulations
The seed heterophase polymerisation as a method of forming crosslinked monodisperse microspheres
Isomerisation of perfluoro(alkenyl vinyl ether) with terminal double bond
Oxidation of hydrolysis lignin with hydrogen peroxide in acid solutions
Prediction of the energy of mechanical failure for elastomers filled with solid particles
Synthesis in a gel and sorption properties of N-2-sulfoethyl chitosan
An IR study of the morphology of polymeric composites
Synthesis of ZnO:Ga nanosized powders by the combustion method
Effect of silica-alumina microspheres on the formation of open porosity in polymeric materials
Synthesis and fungicidal activity of 2-benzoylaminobenzimidazole complex compounds with copper
Copolymerization of modified oligoesteracrylates with oligomeric butadiene rubber
Research of extraction in system Ln(NO$_{3}$)$_{3}$-sodium dodecyl sulfate-isooctyl alcohol
Russian Journal of Applied Chemistry : Volume 86, Issue 1, January 2013
Russian Journal of Applied Chemistry : Volume 85
Russian Journal of Applied Chemistry : Volume 84
Russian Journal of Applied Chemistry : Volume 83
Russian Journal of Applied Chemistry : Volume 82
Russian Journal of Applied Chemistry : Volume 81
Russian Journal of Applied Chemistry : Volume 80
Russian Journal of Applied Chemistry : Volume 79
Russian Journal of Applied Chemistry : Volume 78
Russian Journal of Applied Chemistry : Volume 77
Russian Journal of Applied Chemistry : Volume 76
Russian Journal of Applied Chemistry : Volume 75
Russian Journal of Applied Chemistry : Volume 74

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Cross-linking of oligoalumosiloxanes

Content Provider Springer Nature Link
Author Khelevina, O. G. Malyasova, A. S. Ishutkina, M. V.
Copyright Year 2013
Abstract It is shown that cross-linking of the oligomer Al{[OSi(CH$_{3}$)$_{2}$]$_{290}$OH}$_{3}$ involves terminal hydroxyl groups and is accelerated by the introduction of metalloporphyrazines into the oligomer. The reaction is described by the first-order kinetic equation for irreversible reactions. The effective cross-linking rate constants at 180, 190, and 200°C and the activation energies of the reaction are calculated. A protective material with vulcanized coating based on oligoalumosiloxane has high fire resistance.
Starting Page 141
Ending Page 145
Page Count 5
File Format PDF
ISSN 10704272
Journal Russian Journal of Applied Chemistry
Volume Number 86
Issue Number 2
e-ISSN 16083296
Language English
Publisher SP MAIK Nauka/Interperiodica
Publisher Date 2013-03-15
Publisher Place Dordrecht
Access Restriction One Nation One Subscription (ONOS)
Subject Keyword Chemistry/Food Science Industrial Chemistry/Chemical Engineering
Content Type Text
Resource Type Article
Subject Chemistry Chemical Engineering
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