NDLI: L-proline and l-histidine co-catalyzed Baylis

Please wait, while we are loading the content...

Ligand-free, PdCl$_{2}$(PPh$_{3}$)$_{2}$ catalyzed, microwave-assisted Suzuki coupling of 1-chloro-3-phenylisoquinoline in the synthesis of diversified 1,3-disubstituted isoquinolines

Facile benzannulation of isocoumarins in the efficient synthesis of diversified 1,3-disubstituted isoquinolines

A facile strategy for the synthesis of highly substituted imidazole using tetrabutyl ammoniumbromide as catalyst

Preparation and characterization of Zr-MCM-41 synthesized under microwave irradiation condition for acetylation of 1,2-dimethoxybenzene with acetic anhydride

Electro-catalytic performance of Pt-supported poly (o-phenylenediamine) microrods for methanol oxidation reaction

Knoevenagel condensation of aldehydes with active methylene compounds catalyzed by MgC$_{2}$O$_{4}$/SiO$_{2}$ under microwave irradiation and solvent-free conditions

A simple and efficient synthesis of 1,3,5-tris[2-(3,5-diethynylphenyl)ethynyl]benzene from 1,3,5-triethynylbenzene

Synthesis and regiochemistry of spiro indane-1,3-dione compounds

An unexpected triammine(oxalato)platinum(II) complex obtained from the aqueous solution of tetraammineplatinum(II) oxalate

Indium bromide catalysed, ultrasound-assisted, regio-selective synthesis of ethyl-5-(trifluoromethyl)-1-(3-substituted-isoquinolin-1-yl)-1H-pyrazole-4-carboxylates

Efficient synthesis of AB ring core of luotonin A derivatives: (2-chloroquinolin-3-yl)methanamine

Electrochemical and quantum chemical studies on phthalhydrazide as corrosion inhibitor for mild steel in 1 M HCl solution

The synthesis of novel oxime ethers and their effects on the senescence of cut carnation flowers

Synthesis of zeolites from coal fly ash: application of a statistical experimental design

The photocatalytic properties of amorphous TiO$_{2}$ composite films deposited by magnetron sputtering

A novel synthesis of 2,3-diaminophenazine

Oxidation of d-glucose by N-bromophthalimide in the presence of chlorocomplex of iridium(III): a kinetic and mechanistic study

Synthesis of Er$^{3+}$:Y$_{3}$Al$_{5}$O$_{12}$ and its effects on the solar light photocatalytic activity of TiO$_{2}$–ZrO$_{2}$ composite

Photodegradation of methyl orange from wastewater on TiO$_{2}$/SnS combined powders

Determination of catalytic oxidation products of phenol by RP-HPLC

Cytotoxicity, antioxidant, and antimicrobial activities of novel 2-quinolone derivatives derived from coumarin

Iron-oxide nanoparticles mediated cyclization of 3-(4-chlorophenyl)-1-hydrazinylisoquinoline to 1-(4,5-dihydropyrazol-1-yl)isoquinolines

Thermodynamic studies of methylene blue adsorption onto Fe-doped sulfated titania

Preparation of Cu-doped TiO$_{2}$ via refluxing of alkoxide solution and its photocatalytic properties

An efficient 2-(1H-benzotriazole-1-yl)-1,1,3,3-tetramethyluronium tetrafluoroborate (TBTU)-mediated synthesis of 5-(trifluoromethyl)-N-alkyl-1-(3-phenylisoquinoline-1-yl)-1H-pyrazole-4-carboxamides

Intercalation of Mg–Al layered double hydroxides by l-proline: synthesis and characterization

L-proline and l-histidine co-catalyzed Baylis–Hillman reaction

Oxidizing O,O,O-trimethyl phosphorothioate with hydrogen peroxide or ozone

Study on the synthesis of ZnO/K$_{2}$SO$_{4}$ composite material by sol–gel method and its photocatalytic properties

Preparation, characterization, and theoretical studies of azelaic acid derived from oleic acid by use of a novel ozonolysis method

Evaluation of the inhibitive effect of essential oil of Lavandula multifida L., on the corrosion behavior of C38 steel in 0.5 M H$_{2}$SO$_{4}$ medium

Research on Chemical Intermediates : Volume 38, Issue 1, January 2012

Research on Chemical Intermediates : Volume 37

Research on Chemical Intermediates : Volume 36

Research on Chemical Intermediates : Volume 35

Research on Chemical Intermediates : Volume 34

Research on Chemical Intermediates : Volume 33

Research on Chemical Intermediates : Volume 32

Research on Chemical Intermediates : Volume 31

Research on Chemical Intermediates : Volume 30

Research on Chemical Intermediates : Volume 29

Research on Chemical Intermediates : Volume 28

Research on Chemical Intermediates : Volume 27

Research on Chemical Intermediates : Volume 26

Research on Chemical Intermediates : Volume 25

Research on Chemical Intermediates : Volume 24

Research on Chemical Intermediates : Volume 23

L-proline and l-histidine co-catalyzed Baylis–Hillman reaction

Content Provider	Springer Nature Link
Author	Guo, Peng Fei Wei, Qing Yi Jiang, Hong Xie, Peng Fei
Copyright Year	2011
Abstract	Baylis–Hillman reaction between an aldehyde and an activated alkene, such as alkyl vinyl ketones, acrylates, acrylonitrile, and vinylsulfones, giving the β-hydroxy-α-methylene carbonyl compounds, is a versatile and atom-economical carbon–carbon bond-forming reaction. This reaction usually is catalyzed by strong Lewis bases such as tertiary amines and suffers from slow reaction rate. In this paper the Baylis–Hillman reaction between arylaldehydes and methyl vinyl ketone was successfully realized by a catalytic amount of l-proline and l-histidine system to give the corresponding normal Baylis–Hillman adducts in moderate to high yields for the first time. The effects of solvent and reagent electro property on the yields of this reaction were also investigated. Proline and histidine are naturally widely present amino acids in food system; furthermore, aldehydes and activated alkenes can also be easily produced in food processing, so proline and histidine co-catalyzed Baylis–Hillman reaction may find application in explaining some phenomena in food processing.
Starting Page	639
Ending Page	644
Page Count	6
File Format	PDF
ISSN	09226168
Journal	Research on Chemical Intermediates
Volume Number	38
Issue Number	2
e-ISSN	15685675
Language	English
Publisher	Springer Netherlands
Publisher Date	2011-09-15
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Arylaldehydes Baylis–Hillman reactions Proline Histidine Inorganic Chemistry Physical Chemistry Catalysis
Content Type	Text
Resource Type	Article
Subject	Chemistry

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Baylis-Hillman Reaction of Arylaldehydes with Phenyl Vinyl Ketone, Phenyl Acrylate, and Phenyl Thioacrylate

Enantioselective, Organocatalytic Morita-Baylis-Hillman and Aza-Morita-Baylis-Hillman Reactions: Stereochemical Issues

Promiscuous Lipase-Catalyzed C–C Bond Formation Reactions Between 4 Nitrobenzaldehyde and 2-Cyclohexen-1-one in Biphasic Medium: Aldol and Morita–Baylis–Hillman Adduct Formations

Synthesis of Indenes by Intramolecular Morita-Baylis-Hillman Reaction in Aqueous Media Catalyzed by Resin-Supported Proline

Diels–Alder dimerization of Morita–Baylis–Hillman acetates catalyzed by organocatalysts

DFT exploration of mechanistic pathways of an aza-Morita–Baylis–Hillman reaction

Recyclable hydrotalcite clay catalysed Baylis–Hillman reaction

Synthesis of New Cyano-Quinoline Derivatives by the Baylis–Hillman Reaction

Titanium(IV) Bromide and Boron(III) Tribromide Promoted Baylis-Hillman Reactions of Arylaldehydes with But-3-yn-2-one

L-proline and l-histidine co-catalyzed Baylis–Hillman reaction

Similar Documents

Baylis-Hillman Reaction of Arylaldehydes with Phenyl Vinyl Ketone, Phenyl Acrylate, and Phenyl Thioacrylate

Enantioselective, Organocatalytic Morita-Baylis-Hillman and Aza-Morita-Baylis-Hillman Reactions: Stereochemical Issues

Promiscuous Lipase-Catalyzed C–C Bond Formation Reactions Between 4 Nitrobenzaldehyde and 2-Cyclohexen-1-one in Biphasic Medium: Aldol and Morita–Baylis–Hillman Adduct Formations

Synthesis of Indenes by Intramolecular Morita-Baylis-Hillman Reaction in Aqueous Media Catalyzed by Resin-Supported Proline

Diels–Alder dimerization of Morita–Baylis–Hillman acetates catalyzed by organocatalysts

DFT exploration of mechanistic pathways of an aza-Morita–Baylis–Hillman reaction

Recyclable hydrotalcite clay catalysed Baylis–Hillman reaction

Synthesis of New Cyano-Quinoline Derivatives by the Baylis–Hillman Reaction

Titanium(IV) Bromide and Boron(III) Tribromide Promoted Baylis-Hillman Reactions of Arylaldehydes with But-3-yn-2-one

L-proline and l-histidine co-catalyzed Baylis–Hillman reaction