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Reaction Kinetics and Catalysis Letters : Volume 90, Issue 2, April 2007

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Performance of ionic liquid as catalysts in the synthesis of dimethyl carbonate from ethylene carbonate and methanol

Preparation and photocatalytic behavior of TiO$_{2}$-carbon nanotube hybrid catalyst for acridine dye decomposition

Nanocatalysis in asymmetric hydrogenation

Selective oxidation of isobutane over Mo-V-Te mixed oxide catalysts with different tellurium contents

Cyclotrimerization of an aliphatic aldehyde catalyzed by acidic ionic liquid

Alkylation of benzene with propylene over MCM-36: A comparative study with MCM-22 zeolite synthesized from the same precursors

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Selective ethene homologation reaction on silica supported cobalt catalyst

Application of Et$_{3}$NHCl-AlCl$_{3}$ ionic liquid as an initiator in cationic copolymerization of 1,3-pentadiene with styrene

Epoxidation of cyclohexene on modified Ti-containing mesoporous MCM-41

Kinetic study on degradation of gaseous acetone over thin-film TiO$_{2}$ photocatalyst in a continuous flow system

Studies of the isotopomer determination method for the hydrogen-deuterium exchange of methane. Introduction of methane by a pulse in a deuterium stream at high temperature

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Hydrogenation of nitrate in water over bimetallic Pd-Ag/Al$_{2}$O$_{3}$ catalysts

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Activity of MoSe$_{2}$/Al$_{2}$O$_{3}$ catalysts in decomposition of thiophene and selenophene

Skeletal isomerization of butene over natural ferrierite

Characterization of Au-Rh/TiO$_{2}$ catalysts by CO adsorption; XPS, FTIR and TPD experiments

Hydration of dimethyl ether to methanol over solid acids

Steam reforming of dimethyl ether to hydrogen-rich gas

Experimental study of the gas-phase hydrofluorination of perchloroethylene over a chromium-based catalyst

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Performance of ionic liquid as catalysts in the synthesis of dimethyl carbonate from ethylene carbonate and methanol

Content Provider	Springer Nature Link
Author	Ju, Hye Young Manju, Mamparambath Dharman Park, Dae Won Choe, Youngson Park, Sang Wook
Copyright Year	2007
Abstract	The synthesis of dimethyl carbonate (DMC) from methanol and ethylene carbonate (EC) without using any solvent was investigated in the presence of ionic liquids as catalysts. The conversion of ethylene carbonate was affected by the structure of ionic liquid. For a series of 1-alkyl-3-methylimidazolium ionic liquids, the one with shorter alkyl chain and the one with more nucleophilic anion showed higher reactivity. The conversion of EC also increased with CO$_{2}$ pressure and reaction temperature. Esterification of EC and methanol can be considered as a pseudo-first order reaction with respect to EC concentration. The activation energy was estimated as 50.1 kJ/mol.
Starting Page	3
Ending Page	9
Page Count	7
File Format	PDF
ISSN	01331736
Journal	Reaction Kinetics and Catalysis Letters
Volume Number	90
Issue Number	1
e-ISSN	15882837
Language	English
Publisher	Kluwer Academic Publishers
Publisher Date	2007-01-01
Publisher Place	Dordrecht
Access Restriction	Subscribed
Subject Keyword	Dimethyl carbonate transesterification ethylene carbonate methanol ionic liquid Physical Chemistry Industrial Chemistry/Chemical Engineering Catalysis
Content Type	Text
Resource Type	Article
Subject	Physical and Theoretical Chemistry Catalysis

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