NDLI: Synthesis and structure of crystalline complexes of Np(V) with isophthalic acid. Cation-cation interaction in the compounds [(NpO$_{2}$)$_{2}$(C$_{6}$H$_{4}$(COO)$_{2}$)(H$_{2}$O)]·H$_{2}$O and M[(NpO$_{2}$)(C$_{6}$H$_{4}$(COO)$_{2}$)]·2.5H$_{2}$O, M = [H$_{3}$O], [NH$_{4}$], and [C(NH$_{2}$)$

Content Provider	Springer Nature Link
Author	Grigor’ev, M. S. Charushnikova, I. A. Fedoseev, A. M.
Copyright Year	2015
Abstract	New Np(V) isophthalate complexes of the compositions [(NpO$_{2}$)$_{2}$(C$_{6}$H$_{4}$(COO)$_{2}$)(H$_{2}$O)]·H$_{2}$O (I) and M[(NpO$_{2}$)(C$_{6}$H$_{4}$(COO)$_{2}$)]·nH$_{2}$O, where M = [H$_{3}$O] (IIa), [NH$_{4}$] (IIb), and [C(NH$_{2}$)$_{3}$] (IIc), were synthesized and studied by single crystal X-ray diffraction. Cation-cation interaction was revealed in their structure. In the structure of I, each of three nonequivalent NpO$_{2}$ groups is a bidentate ligand and simultaneously coordinates two adjacent neptunyl(V) ions to form “square” cationic networks. The cationic networks in the crystal are linked by bridging [C$_{6}$H$_{4}$(COO)$_{2}$]$^{2−}$ anions exhibiting the coordination capacity equal to 5. Three independent Np atoms are characterized by different shapes of the coordination polyhedron (CP): hexagonal, pentagonal, and tetragonal bipyramids. Tetrameric cationic complexes in which each NpO$_{2}$ group is a monodentate ligand and a coordination center for the adjacent group are formed in the structure of II. The cationic complexes are linked by the bridging [C$_{6}$H$_{4}$(COO)$_{2}$]$_{2−}$ anions whose coordination capacity is 4; the CPs of the Np atoms are pentagonal bipyramids. In the structure of II, replacement of relatively small outer-sphere hydroxonium and ammonium cations by guanidinium cation does not alter the overall structural motif of the crystal.
Starting Page	386
Ending Page	394
Page Count	9
File Format	PDF
ISSN	10663622
Journal	Radiochemistry
Volume Number	57
Issue Number	4
e-ISSN	16083288
Language	English
Publisher	Pleiades Publishing
Publisher Date	2015-08-02
Publisher Place	Moscow
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	neptunium(V) isophthalate cation-cation interaction crystal structure Nuclear Chemistry Chemistry/Food Science
Content Type	Text
Resource Type	Article
Subject	Physical and Theoretical Chemistry

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Crystal structure of mixed-valent Np(IV)/Np(V) chloride, [Np(NpO$_{2}$)$_{6}$(H$_{2}$O)$_{8}$(OH)Cl$_{9}$]·H$_{2}$O

Synthesis and structure of dimeric complexes of U(VI) and Np(VI) with isophthalic acid anions, {AnO$_{2}$[C$_{6}$H$_{4}$(COO)(COOH)]$_{2}$(H$_{2}$O)}$_{2}$

Crystal structure of a double Np(V) ammonium propionate, NH$_{4}$[(NpO$_{2}$)$_{3}$(C$_{2}$H$_{5}$COO)$_{4}$(H$_{2}$O)]·3H$_{2}$O

Synthesis, crystal structure, and spectra of the Np(V) terephthalate [C(NH$_{2}$)$_{3}$]$_{3}$[NpO$_{2}$(C$_{6}$H$_{4}$(COO)$_{2}$)$_{2}$]·5H$_{2}$O and An(VI) terephthalates [AnO$_{2}$(C$_{6}$H$_{4}$(COO)$_{2}$)] (An = U, Np, Pu)

Cation-cation interaction in mixed-valent An(IV)/Np(V) tribromoacetates [An(NpO$_{2}$)(H$_{2}$O)$_{3}$(CBr$_{3}$COO)$_{5}$]·CBr$_{3}$COOH·nH$_{2}$O, An = Th(IV), Np(IV)

Cation–cation interaction in mixed-element Th(IV)/Np(V) chlorides, [Th(NpO$_{2}$)$_{6}$(H$_{2}$O)$_{8}$(OH)Cl$_{9}$]·H$_{2}$O and [Th(NpO$_{2}$)$_{6}$(H$_{2}$O)$_{9}$Cl$_{9}$]Cl

Cation-cation interaction in the double Th(IV)/Np(V) nitrate [H$_{3}$O][Th$_{2}$(NpO$_{2}$)$_{3}$(H$_{2}$O)$_{9}$(NO$_{3}$)$_{12}$]·2H$_{2}$O

Crystal structure of a double Np(V) and Co(NH$_{3}$) 6 3+ maleate, Co(NH$_{3}$)$_{6}$[NpO$_{2}$(HL)$_{2}$(H$_{2}$O)$_{3}$](HL)$_{2}$•H$_{2}$O [L = OOC(HC)$_{2}$COO]

Crystal Structure of Double Co(NH$_{3}$)$_{6}$ $^{3}$ $^{+}$ Np(V) Malonates Co(NH$_{3}$)$_{6}$(NpO$_{2}$C$_{3}$H$_{2}$O$_{4}$)$_{2}$A·H$_{2}$O (A = OH and NO$_{3}$)

Similar Documents

Crystal structure of mixed-valent Np(IV)/Np(V) chloride, [Np(NpO$_{2}$)$_{6}$(H$_{2}$O)$_{8}$(OH)Cl$_{9}$]·H$_{2}$O

Synthesis and structure of dimeric complexes of U(VI) and Np(VI) with isophthalic acid anions, {AnO$_{2}$[C$_{6}$H$_{4}$(COO)(COOH)]$_{2}$(H$_{2}$O)}$_{2}$

Crystal structure of a double Np(V) ammonium propionate, NH$_{4}$[(NpO$_{2}$)$_{3}$(C$_{2}$H$_{5}$COO)$_{4}$(H$_{2}$O)]·3H$_{2}$O

Synthesis, crystal structure, and spectra of the Np(V) terephthalate [C(NH$_{2}$)$_{3}$]$_{3}$[NpO$_{2}$(C$_{6}$H$_{4}$(COO)$_{2}$)$_{2}$]·5H$_{2}$O and An(VI) terephthalates [AnO$_{2}$(C$_{6}$H$_{4}$(COO)$_{2}$)] (An = U, Np, Pu)

Cation-cation interaction in mixed-valent An(IV)/Np(V) tribromoacetates [An(NpO$_{2}$)(H$_{2}$O)$_{3}$(CBr$_{3}$COO)$_{5}$]·CBr$_{3}$COOH·nH$_{2}$O, An = Th(IV), Np(IV)

Cation–cation interaction in mixed-element Th(IV)/Np(V) chlorides, [Th(NpO$_{2}$)$_{6}$(H$_{2}$O)$_{8}$(OH)Cl$_{9}$]·H$_{2}$O and [Th(NpO$_{2}$)$_{6}$(H$_{2}$O)$_{9}$Cl$_{9}$]Cl

Cation-cation interaction in the double Th(IV)/Np(V) nitrate [H$_{3}$O][Th$_{2}$(NpO$_{2}$)$_{3}$(H$_{2}$O)$_{9}$(NO$_{3}$)$_{12}$]·2H$_{2}$O

Crystal structure of a double Np(V) and Co(NH$_{3}$) 6 3+ maleate, Co(NH$_{3}$)$_{6}$[NpO$_{2}$(HL)$_{2}$(H$_{2}$O)$_{3}$](HL)$_{2}$•H$_{2}$O [L = OOC(HC)$_{2}$COO]

Crystal Structure of Double Co(NH$_{3}$)$_{6}$ $^{3}$ $^{+}$ Np(V) Malonates Co(NH$_{3}$)$_{6}$(NpO$_{2}$C$_{3}$H$_{2}$O$_{4}$)$_{2}$A·H$_{2}$O (A = OH and NO$_{3}$)